King's College London

Research portal

Dr Graeme Hogarth

  1. Hydrogenase biomimics containing redox-active ligands: Fe2(CO)4(μ-edt)(κ2-bpcd) with electron-acceptor 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) as a potential [Fe4–S4]H surrogate

    Ghosh, S., Hollingsworth, N., Warren, M., Hrovat, D. A., Richmond, M. G. & Hogarth, G., 14 May 2019, In : Dalton Transactions. 48, 18, p. 6051-6060 10 p.

    Research output: Contribution to journalArticle

  2. Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(ii) centre: A convenient synthesis of Ni(ii)-thiolate complexes

    Al-Jibori, S. A., Ali, S. H., Al-Janabi, A. S., Wagner, C. & Hogarth, G., 23 Apr 2019, In : Dalton Transactions. 48, 17, p. 5520-5522 3 p.

    Research output: Contribution to journalArticle

  3. Models of the iron-only hydrogenase enzyme: structure, electrochemistry and catalytic activity of Fe 2 (CO) 3 (μ-dithiolate)(μ,κ 1 ,κ 2 -triphos)

    Unwin, D. G., Ghosh, S., Ridley, F., Richmond, M. G., Holt, K. B. & Hogarth, G., 27 Mar 2019, In : Dalton Transactions. 48, 18, p. 6174-6190 17 p.

    Research output: Contribution to journalArticle

  4. Synthesis and reactivity towards amines of benzisothiazolinate-bridged paddlewheel dimers [M2(μ-bit)4·2H2O] (M = Mn, Co, Ni, Cu)

    Al-Jibori, S. A., Al-Jibori, A. R., Mohamad, H. A., Al-Janabi, A. S., Wagner, C. & Hogarth, G., 24 Mar 2019, In : INORGANICA CHIMICA ACTA. 488, p. 152-158 7 p.

    Research output: Contribution to journalArticle

  5. Highly efficient electrocatalytic proton-reduction by coordinatively and electronically unsaturated Fe(CO)(κ2-dppn)(κ2-tdt)

    Ghosh, S., Rana, S., Kabir, S. E., Richmond, M. G. & Hogarth, G., 24 Feb 2019, In : INORGANICA CHIMICA ACTA. 486, p. 435-440 6 p.

    Research output: Contribution to journalArticle

  6. An atom efficient, single-source precursor route to plasmonic CuS nanocrystals

    Mann, P. B., Mcgregor, I. J., Bourke, S., Burkitt-gray, M., Fairclough, S., Ma, M. T., Hogarth, G., Thanou, M., Long, N. & Green, M., 1 Feb 2019, In : Nanoscale Advances. 1, 2, p. 522-526 5 p.

    Research output: Contribution to journalArticle

  7. Chalcogenide-capped triiron clusters [Fe3(CO)9(μ3-E)2], [Fe3(CO)7(μ3-CO)(μ3-E)(μ-dppm)] and [Fe3(CO)7(μ3-E)2(μ-dppm)] (E = S, Se) as proton-reduction catalysts

    Rahaman, A., Ghosh, S., Basak-Modi, S., Abdel-Magied, A. F., Kabir, S. E., Haukka, M., Richmond, M. G., Lisensky, G., Nordlander, E. & Hogarth, G., 1 Feb 2019, In : JOURNAL OF ORGANOMETALLIC CHEMISTRY. 880, p. 213-222 10 p.

    Research output: Contribution to journalArticle

  8. Chemistry, pharmacology, and cellular uptake mechanisms of thiometallate sulfide donors

    Durham, T., Zander, D., Stomeo, N., Minnion, M., Hogarth, G., Feelisch, M., Singer, M. & Dyson, A., 1 Jan 2019, In : British Journal of Pharmacology.

    Research output: Contribution to journalArticle

  9. New molecular architectures containing low-valent cluster centres with di- and trimetalated 2-vinylpyrazine ligands: Synthesis and molecular structures of Ru5(CO)155-C4H2N2CHCH)(μ-H)2 and Ru8(CO)247-C4H2N2CHC)(μ-H)3

    Hossain, M. M., Akter, N., Ghosh, S., Nesterov, V. N., Richmond, M. G., Hogarth, G. & Kabir, S. E., 1 Jan 2019, In : RSC Advances. 9, 36, p. 21025-21030 6 p.

    Research output: Contribution to journalArticle

  10. Hydrogenase biomimetics with redox-active ligands: Synthesis, structure, and electrocatalytic studies on [Fe2(CO)42-dppn)(μ-edt)] (edt = ethanedithiolate; dppn = 1,8-bis(diphenylphosphino)naphthalene)

    Ghosh, S., Rana, S., Hollingsworth, N., Richmond, M. G., Kabir, S. E. & Hogarth, G., 20 Nov 2018, In : Inorganics. 6, 4, p. 1-14 14 p., 122.

    Research output: Contribution to journalArticle

  11. Insight into Nature of Iron Sulfide Surfaces during the Electrochemical Hydrogen Evolution and CO2 Reduction Reactions

    Zakaria, S. N. A., Hollingsworth, N., Islam, H., Roffey, A., Santos-Carballal, D., Roldan, A., Bras, W., Sankar, G., Hogarth, G., Holt, K. B. & de Leeuw, N. H., 20 Jul 2018, In : ACS Applied Materials and Interfaces.

    Research output: Contribution to journalArticle

  12. Electrocatalytic proton reduction by thiolate-capped triiron clusters [Fe3(CO)9(μ3-SR)(μ-H)] (R = iPr, tBu)

    Ghosh, S., Basak-Modi, S., Richmond, M. G., Nordlander, E. & Hogarth, G., 30 Apr 2018, In : INORGANICA CHIMICA ACTA.

    Research output: Contribution to journalArticle

  13. Mixed-valence dimolybdenum complexes containing hard oxo and soft carbonyl ligands: synthesis, structure, and electrochemistry of Mo2(O)(CO)2(μ-κ2-S(CH2)nS)22-diphosphine)

    Haque, M. R., Ghosh, S., Rahman, M. M., Siddiquee, T. A., Nesterov, V. N., Richmond, M. G., Hogarth, G. & Kabir, S. E., 2018, In : Dalton Transactions. 47, 30, p. 10102-10112 11 p.

    Research output: Contribution to journalArticle

  14. Electrocatalytic proton reduction by [Fe(CO)22-dppv)(κ1-SAr)2] (dppv = cis-1,2-bis(diphenylphosphino)ethylene; Ar = C6F5, C6H5, C6H4CH3-p)

    Ghosh, S., Hollingsworth, N., Warren, M., Holt, K. B. & Hogarth, G., 24 Nov 2017, In : POLYHEDRON. 137, p. 140-146 7 p.

    Research output: Contribution to journalArticle

  15. Fe2(CO)9 and friends: Four Billion Years of Diiron Chemistry

    Hogarth, G., 20 Sep 2017, Specialist Periodical Reoprts: Organometallic Chemistry. Lynam, J. M. (ed.). London: Royal Society of Chemistry, Vol. 41. p. 48-92 44 p. DOI: 10.1039/9781782626923-00048

    Research output: Chapter in Book/Report/Conference proceedingChapter

  16. Induction of Necroptosis in Cancer Stem Cells by a Nickel(II)-Dithiocarbamate Phenanthroline Complex

    Flamme, M., Cressey, P. B., Lu, C., Bruno, P. M., Eskandari, A., Hemann, M. T., Hogarth, G. & Suntharalingam, K., 18 Jul 2017, In : CHEMISTRY. 23, 40, p. 9674–9682 9 p.

    Research output: Contribution to journalArticle

  17. Mixed main group transition metal clusters: Reactions of [Ru3(CO)10(μ-dppm)] with Ph3SnH

    Mahabub Khan, M. M., Ghosh, S., Hogarth, G., Tocher, D. A., Richmond, M. G., Kabir, S. E. & Roesky, H. W., 1 Jul 2017, In : JOURNAL OF ORGANOMETALLIC CHEMISTRY. 840, p. 47-55

    Research output: Contribution to journalArticle

  18. Reversible C-H bond activation at a triosmium centre: A comparative study of the reactivity of unsaturated triosmium clusters Os3(CO)8(μ-dppm)(μ-H)2 and Os3(CO)8(μ-dppf)(μ-H)2 with activated alkynes

    Chowdhury, M. A. H., Haque, M. R., Ghosh, S., Mobin, S. M., Tocher, D. A., Hogarth, G., Richmond, M. G., Kabir, S. E. & Roesky, H. W., 28 Feb 2017, In : JOURNAL OF ORGANOMETALLIC CHEMISTRY. 13 p.

    Research output: Contribution to journalArticle

  19. Accepted/In press
  20. Monofunctional platinum(ii) dithiocarbamate complexes: synthesis, characterization and anticancer activity

    Amir, M. K., Zia-Ur-Rehman, Hayat, F., Khan, S. Z., Hogarth, G., Kondratyuk, T., Pezzuto, JM. & Tahir, M. N., 11 Nov 2016, In : RSC Advances. 6, 112, p. 110517-110524 8 p.

    Research output: Contribution to journalArticle

  21. Biomimetics of the [FeFe]-hydrogenase enzyme: Identification of kinetically favoured apical-basal [Fe2(CO)4(μ-H){κ2-Ph2PC(Me2)PPh2}(μ-pdt)]+ as a proton-reduction catalyst 

    Ghosh, S., Sanchez, B. E., Richards, I., Haque, M. N., Holt, K. B., Richmond, M. G. & Hogarth, G., 15 Jun 2016, In : JOURNAL OF ORGANOMETALLIC CHEMISTRY. 812, p. 247-258 12 p.

    Research output: Contribution to journalArticle

  22. Oxidative-addition of germanium-hydrogen bonds to triosmium centers: Reactions of Os3(CO)10(μ-dppm) and Os3(CO)83-Ph2PCH2P(Ph)C6H4)(μ-H) with Ph3GeH

    Haque, M. R., Hossain, M. J., Rahaman, A., Ghosh, S., Kabir, S. E., Hogarth, G. & Tocher, D. A., 15 Jun 2016, In : JOURNAL OF ORGANOMETALLIC CHEMISTRY. 812, p. 240-246 7 p.

    Research output: Contribution to journalArticle

  23. Phase control during the synthesis of nickel sulfide nanoparticles from dithiocarbamate precursors

    Roffey, A., Hollingsworth, N., Islam, H-U., Mercy, M., Sankar, G., Catlow, C. R. A., Hogarth, G. & de Leeuw, N. H., 25 May 2016, In : Nanoscale. 8, p. 11067-11075 9 p.

    Research output: Contribution to journalArticle

  24. Hydrogenase biomimetics with redox-active ligands: Electrocatalytic proton reduction by [Fe2(CO)4(κ2-diamine)(μ-edt)] (diamine = 2,2′-bipy, 1,10-phen)

    Ghosh, S., Rahaman, A., Holt, K. B., Nordlander, E., Richmond, M. G., Kabir, S. E. & Hogarth, G., 14 May 2016, In : POLYHEDRON.

    Research output: Contribution to journalArticle

  25. Synthesis and molecular structures of palladium(II) metalated 2-phenylpyridine complexes [PdCl(pyC6H4)L] containing amino- or acetylamino-pyridine co-ligands

    Al-Jibori, S. A., Gergees, H. M., Al-Rubaye, M. S., Basak-Modi, S., Ghosh, S., Schmidt, H., Laguna, M., Asunción Luquin Martínez, M. & Hogarth, G., 9 May 2016, In : INORGANICA CHIMICA ACTA.

    Research output: Contribution to journalArticle

  26. Iron carbonyl complexes bearing phenazine and acridine ligands: X-ray structures of Fe(CO)34-C12H8N2), Fe(CO)2{P(OMe)3}(η4-C12H8N2), Fe(CO)2(PPh3) (η4-C13H9N), and Fe(CO)21-dppm) (η4-C12H8N2)

    Chowdhury, M. A. H., Rahman, M. S., Islam, M. R., Rajbangshi, S., Ghosh, S., Hogarth, G., Tocher, D. A., Yang, L., Richmond, M. G. & Kabir, S. E., 1 Mar 2016, In : JOURNAL OF ORGANOMETALLIC CHEMISTRY. 805, p. 34-41 8 p.

    Research output: Contribution to journalArticle

  27. Oxidative-addition of the N-H bond of saccharin (sacH) to a triosmium centre: Synthesis, structure and reactivity of Os3(CO)10(μ-H)(μ-sac) 

    Monira, S., Afrin, S., Azam, K. A., Hossain, M. K., Tocher, D. A., Ghosh, S., Rajbangshi, S., Kabir, S. E. & Hogarth, G., 15 Dec 2015, In : JOURNAL OF ORGANOMETALLIC CHEMISTRY. 799-800, p. 281-290 10 p.

    Research output: Contribution to journalArticle

  28. Palladium(II) benzisothiazolinate (bit) complexes with amino-, acetylamino-, heterocyclic and phosphine co-ligands. Crystal structure of [Pd(bit)22-dppe)]·2EtOH

    Al-Jibori, S. A., Ahmed, B. S. M., Ahmed, S. A., Karadaʇ, A., Schmidt, H., Wagner, C. & Hogarth, G., 1 Sep 2015, In : INORGANICA CHIMICA ACTA. 436, p. 7-15 9 p., 16598.

    Research output: Contribution to journalArticle

  29. Formation of ortho-cyano-aminothiophenolate ligands with versatile binding modes via facile carbon-sulfur bond cleavage of 2-aminobenzothiazoles at mercury(II) centres

    Al-Jibori, S. A., Irzoqi, A. A., Al-Saraj, E. G. H., Al-Janabi, A. S. M., Basak-Modi, S., Ghosh, S., Merzweiler, K., Wagner, C., Schmidt, H. & Hogarth, G., 28 Aug 2015, In : Dalton transactions (Cambridge, England : 2003). 44, 32, p. 14217-14219 3 p.

    Research output: Contribution to journalArticle

  30. Synthesis, structure and bonding of new mono- and dinuclear molybdenum complexes containing pyridine-2-thiolate (pyS) and different P-donors

    Haque, M. R., Ghosh, S., Hogarth, G., Richmond, M. G. & Kabir, S. E., 11 Jun 2015, In : INORGANICA CHIMICA ACTA. 434, p. 150-157 8 p.

    Research output: Contribution to journalArticle

  31. Multimetallic complexes based on a diphosphine-dithiocarbamate "janus" ligand

    Sherwood, R., Gonzàlez De Rivera, F., Wan, J. H., Zhang, Q., White, A. J. P., Rossell, O., Hogarth, G. & Wilton-Ely, J. D. E. T., 4 May 2015, In : INORGANIC CHEMISTRY. 54, 9, p. 4222-4230 9 p.

    Research output: Contribution to journalArticle

  32. Bio-Inspired CO2 Conversion by Iron Sulfide Catalysts under Sustainable Conditions

    Roldan, A., Hollingsworth, N., Roffey, A., Islam, H-U., Goodall, J. B. M., Catlow, C. R. A., Darr, J. A., Bras, W., Sankar, G., Holt, K. B., Hogarth, G. & de Leeuw, N. H., 1 May 2015, In : CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRY. 51, p. 7501-7504 3 p.

    Research output: Contribution to journalArticle

  33. Doping group IIB metal ions into quantum dot shells via the one-pot decomposition of metal-dithiocarbamates

    Bear, J. C., Hollingsworth, N., Roffey, A., Mcnaughter, P. D., Mayes, A. G., Macdonald, T. J., Nann, T., Ng, W. H., Kenyon, A. J., Hogarth, G. & Parkin, I. P., May 2015, In : Advanced Optical Materials.

    Research output: Contribution to journalArticle

  34. Reactions of [CpM(CO)3]2(M = Mo, W) with Ph3SnSR: Formation of CpM(CO)3(SnPh3) and CpM(CO)2(2-SR) via Sn-S bond cleavage

    Al-Mamun, M. R., Ghosh, S., Kabir, S. E., Sarker, J. C., Hogarth, G. & Nicholson, B. K., 22 Apr 2015, In : JOURNAL OF COORDINATION CHEMISTRY. 68, 11, p. 1903-1912 10 p.

    Research output: Contribution to journalArticle

  35. Copper catalysed amidation of aryl halides through chelation assistance

    Kathiravan, S., Ghosh, S., Hogarth, G. & Nicholls, I. A., 21 Mar 2015, In : CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRY. 51, 23, p. 4834-4837 4 p.

    Research output: Contribution to journalArticle

  36. Combining anti-cancer drugs with artificial sweeteners: Synthesis and anti-cancer activity of saccharinate (sac) and thiosaccharinate (tsac) complexes cis-[Pt(sac)2(NH3)2] and cis-[Pt(tsac)2(NH3)2]

    Al-jibori, S. A., Al-jibori, G. H., Al-hayaly, L. J., Wagner, C., Schmidt, H., Timur, S., Baris Barlas, F., Subasi, E., Ghosh, S. & Hogarth, G., 1 Dec 2014, In : Journal of Inorganic Biochemistry. 141, p. 55-57 3 p.

    Research output: Contribution to journalArticle

  37. Mercury(II) saccharinate (sac) complexes: Synthesis and molecular structures of [Hg(sac)2(2-ampy)2], [Hg(sac)2(2-ampy)(MeOH)], [Hg(sac)2(2-abt)(MeOH)], [Hg(sac)2(2-abt)(dmso)] (2-ampy=2-aminopyridine, 2-abt=2-aminobenzothiazole)

    Al-jibori, S. A., Afandi, Z. S., Merzweiler, K., Wagner, C., Schmidt, H., Basak-modi, S. & Hogarth, G., 15 Oct 2014, In : POLYHEDRON. 81, p. 442-449 8 p.

    Research output: Contribution to journalArticle

  38. Palladium(II) saccharinate complexes trans-[Pd(sac)2(LH)2] with amino- and acetylamino-pyridine co-ligands: molecular structures of trans-[PdCl2(2-ampyH)2].2dmf (2-ampyH = 2-amino-3-methylpyridine) and trans-[Pd(κ2-2-acmpy)2] (2-acmpyH = 2-acetylamino-3-methylpyridine)

    Al-jibori, S. A., Al-nassiry, R. A. Q., Al-jibori, G. H. H., Merzweiler, K., Wagner, C., Schmidt, H., Basak-modi, S. & Hogarth, G., 1 Oct 2014, In : Transition Metal Chemistry. 39, 7, p. 735-740 6 p.

    Research output: Contribution to journalArticle

  39. Experimental and computational studies on the reaction of silanes with the diphosphine-bridged triruthenium clusters Ru-3(CO)(10)(mu-dppf), Ru-3(CO)(10)(mu-dppm) and Ru-3(CO)(9){mu(3)-PPhCH2PPh(C6H4)}

    Hossain, M. J., Rajbangshi, S., Khan, M. M. M., Ghosh, S., Hogarth, G., Rosenberg, E., Hardcastle, K. I., Richmond, M. G. & Kabir, S. E., 15 Sep 2014, In : JOURNAL OF ORGANOMETALLIC CHEMISTRY. 767, p. 185-195 11 p.

    Research output: Contribution to journalArticle

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