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An Endergonic Synthesis of Single Sondheimer-Wong Diyne by Local Probe Chemistry

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Shigeki Kawai, Hongqian Sang, Lev Kantorovich, Keisuke Takahashi, Kyoko Nozaki, Shingo Ito

Original languageEnglish
JournalANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Accepted/In press17 Mar 2020

King's Authors

Abstract

Recent advances in scanning probe microscopy on surface enable not only direct observation of molecular structures but also local probe reactions, in which unstable short-lived products have been synthesized and analyzed. Here, we demonstrate an endergonic reaction to synthesize a single Sondheimer-Wong diyne from 6,13-dibromopentaleno[1,2-b:4,5- b’]dinaphthalene by local probe chemistry on a ultra-thin film of NaCl formed on a Cu(111) surface at 4.3 K. The structures of the precursor and two intermediates, as well as the final product, were directly identified by the differential conductance imaging with a CO functionalized tip. Our density functional theory calculations revealed that the multiple steps reaction, being endergonic overall, is facilitated by temporal charging and discharging of the molecule placed in the nanometric junction between the Cu tip and the Cu substrate underneath the ultra-thin NaCl film. This local probe reaction expands possibilities to synthesize various nano-carbon materials in a bottom-up manner.

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