Crystal structure of [butane-2,3-dione bis(4-methylthiosemicarbazonato)-κ4 S,N1,N1′,S′](pyridine-κN)zinc(II)

Oliver C. Brown; Derek A. Tocher; Philip J. Blower; Michael J. Went

doi:10.1107/S2056989015019234

Crystal structure of [butane-2,3-dione bis(4-methylthiosemicarbazonato)-κ⁴ S,N¹,N^1′,S′](pyridine-κN)zinc(II)

Oliver C. Brown, Derek A. Tocher, Philip J. Blower, Michael J. Went^*

^*Corresponding author for this work

Imaging Chemistry & Biology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In the structure of the title complex, [Zn(C₈H₁₄N₆S₂)(C₅H₅N)], the Zn^II ion has a pseudo-square-pyramidal coordination environment and is displaced by 0.490 Å from the plane of best fit defined by the bis(thiosemicarbazonate) N₂S₂ donor atoms. Chains sustained by intermolecular N - H⋯N and N - H⋯S hydrogen-bonding interactions extend parallel to [10-1].

Original language	English
Pages (from-to)	1349-1351
Number of pages	3
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	71
DOIs	https://doi.org/10.1107/S2056989015019234
Publication status	Published - 1 Jan 2015

Keywords

bis(thiosemicarbazone)
copper
crystal structure
hypoxia
PET
zinc

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title = "Crystal structure of [butane-2,3-dione bis(4-methylthiosemicarbazonato)-κ4 S,N1,N1′,S′](pyridine-κN)zinc(II)",

abstract = "In the structure of the title complex, [Zn(C8H14N6S2)(C5H5N)], the ZnII ion has a pseudo-square-pyramidal coordination environment and is displaced by 0.490 {\AA} from the plane of best fit defined by the bis(thiosemicarbazonate) N2S2 donor atoms. Chains sustained by intermolecular N - H⋯N and N - H⋯S hydrogen-bonding interactions extend parallel to [10-1].",

keywords = "bis(thiosemicarbazone), copper, crystal structure, hypoxia, PET, zinc",

author = "Brown, {Oliver C.} and Tocher, {Derek A.} and Blower, {Philip J.} and Went, {Michael J.}",

year = "2015",

month = jan,

day = "1",

doi = "10.1107/S2056989015019234",

language = "English",

volume = "71",

pages = "1349--1351",

journal = "Acta Crystallographica Section E: Crystallographic Communications",

issn = "2056-9890",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Crystal structure of [butane-2,3-dione bis(4-methylthiosemicarbazonato)-κ4 S,N1,N1′,S′](pyridine-κN)zinc(II)

AU - Brown, Oliver C.

AU - Tocher, Derek A.

AU - Blower, Philip J.

AU - Went, Michael J.

PY - 2015/1/1

Y1 - 2015/1/1

N2 - In the structure of the title complex, [Zn(C8H14N6S2)(C5H5N)], the ZnII ion has a pseudo-square-pyramidal coordination environment and is displaced by 0.490 Å from the plane of best fit defined by the bis(thiosemicarbazonate) N2S2 donor atoms. Chains sustained by intermolecular N - H⋯N and N - H⋯S hydrogen-bonding interactions extend parallel to [10-1].

AB - In the structure of the title complex, [Zn(C8H14N6S2)(C5H5N)], the ZnII ion has a pseudo-square-pyramidal coordination environment and is displaced by 0.490 Å from the plane of best fit defined by the bis(thiosemicarbazonate) N2S2 donor atoms. Chains sustained by intermolecular N - H⋯N and N - H⋯S hydrogen-bonding interactions extend parallel to [10-1].

KW - bis(thiosemicarbazone)

KW - copper

KW - crystal structure

KW - hypoxia

KW - PET

KW - zinc

UR - http://www.scopus.com/inward/record.url?scp=84948463202&partnerID=8YFLogxK

U2 - 10.1107/S2056989015019234

DO - 10.1107/S2056989015019234

M3 - Article

AN - SCOPUS:84948463202

SN - 2056-9890

VL - 71

SP - 1349

EP - 1351

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

ER -

Crystal structure of [butane-2,3-dione bis(4-methylthiosemicarbazonato)-κ⁴ S,N¹,N^1′,S′](pyridine-κN)zinc(II)

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Keywords

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