Crystal structure of fac-tricarbonyl(quinoline-2-carboxylato-j2N,O)(triphenylarsane-jAs)-rhenium(I)

Charalampos Triantis; Antonio Shegani; Christos Kiritsis; Catherine P. Raptopoulou; Vassilis Psycharis; Maria Pelecanou; Ioannis Pirmettisa; Minas Papadopoulos

doi:10.1107/S2056989015024640

Crystal structure of fac-tricarbonyl(quinoline-2-carboxylato-j2N,O)(triphenylarsane-jAs)-rhenium(I)

Charalampos Triantis, Antonio Shegani, Christos Kiritsis, Catherine P. Raptopoulou, Vassilis Psycharis^*, Maria Pelecanou, Ioannis Pirmettisa, Minas Papadopoulos

^*Corresponding author for this work

Imaging Chemistry & Biology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In the title compound, [Re(C₁₀H₆NO₂)(CO)₃{As(C₆H₅)₃}], the coordination environment of ReI is that of a distorted octahedron. Three coordination sites are occupied by three carbonyl groups in a facial arrangement and the remaining three sites by triphenylarsane and deprotonated quinaldic acid in As-mono-and N,O-bidentate fashions, respectively. In the crystal, the complexes are linked through weak C-H.O hydrogen bonds, forming a three-dimensional network. It worth noting that, as far as we know, this complex is the first ReI triphenylarsane tricarbonyl compound to be reported.

Original language	English
Pages (from-to)	114-116
Number of pages	3
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	72
Issue number	2
DOIs	https://doi.org/10.1107/S2056989015024640
Publication status	Published - Feb 2016

Keywords

Crystal structure
rhenium(I) tricarbonyl complex
rhenium(I) triphenylarsane and quinaldic acid complex
trans influence

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10.1107/S2056989015024640

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title = "Crystal structure of fac-tricarbonyl(quinoline-2-carboxylato-j2N,O)(triphenylarsane-jAs)-rhenium(I)",

abstract = "In the title compound, [Re(C10H6NO2)(CO)3{As(C6H5)3}], the coordination environment of ReI is that of a distorted octahedron. Three coordination sites are occupied by three carbonyl groups in a facial arrangement and the remaining three sites by triphenylarsane and deprotonated quinaldic acid in As-mono-and N,O-bidentate fashions, respectively. In the crystal, the complexes are linked through weak C-H.O hydrogen bonds, forming a three-dimensional network. It worth noting that, as far as we know, this complex is the first ReI triphenylarsane tricarbonyl compound to be reported.",

keywords = "Crystal structure, rhenium(I) tricarbonyl complex, rhenium(I) triphenylarsane and quinaldic acid complex, trans influence",

author = "Charalampos Triantis and Antonio Shegani and Christos Kiritsis and Raptopoulou, {Catherine P.} and Vassilis Psycharis and Maria Pelecanou and Ioannis Pirmettisa and Minas Papadopoulos",

year = "2016",

month = feb,

doi = "10.1107/S2056989015024640",

language = "English",

volume = "72",

pages = "114--116",

journal = "Acta Crystallographica Section E: Crystallographic Communications",

issn = "2056-9890",

publisher = "International Union of Crystallography",

number = "2",

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TY - JOUR

T1 - Crystal structure of fac-tricarbonyl(quinoline-2-carboxylato-j2N,O)(triphenylarsane-jAs)-rhenium(I)

AU - Triantis, Charalampos

AU - Shegani, Antonio

AU - Kiritsis, Christos

AU - Raptopoulou, Catherine P.

AU - Psycharis, Vassilis

AU - Pelecanou, Maria

AU - Pirmettisa, Ioannis

AU - Papadopoulos, Minas

PY - 2016/2

Y1 - 2016/2

N2 - In the title compound, [Re(C10H6NO2)(CO)3{As(C6H5)3}], the coordination environment of ReI is that of a distorted octahedron. Three coordination sites are occupied by three carbonyl groups in a facial arrangement and the remaining three sites by triphenylarsane and deprotonated quinaldic acid in As-mono-and N,O-bidentate fashions, respectively. In the crystal, the complexes are linked through weak C-H.O hydrogen bonds, forming a three-dimensional network. It worth noting that, as far as we know, this complex is the first ReI triphenylarsane tricarbonyl compound to be reported.

AB - In the title compound, [Re(C10H6NO2)(CO)3{As(C6H5)3}], the coordination environment of ReI is that of a distorted octahedron. Three coordination sites are occupied by three carbonyl groups in a facial arrangement and the remaining three sites by triphenylarsane and deprotonated quinaldic acid in As-mono-and N,O-bidentate fashions, respectively. In the crystal, the complexes are linked through weak C-H.O hydrogen bonds, forming a three-dimensional network. It worth noting that, as far as we know, this complex is the first ReI triphenylarsane tricarbonyl compound to be reported.

KW - Crystal structure

KW - rhenium(I) tricarbonyl complex

KW - rhenium(I) triphenylarsane and quinaldic acid complex

KW - trans influence

UR - http://www.scopus.com/inward/record.url?scp=84988468557&partnerID=8YFLogxK

U2 - 10.1107/S2056989015024640

DO - 10.1107/S2056989015024640

M3 - Article

AN - SCOPUS:84988468557

SN - 2056-9890

VL - 72

SP - 114

EP - 116

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

IS - 2

ER -

Crystal structure of fac-tricarbonyl(quinoline-2-carboxylato-j2N,O)(triphenylarsane-jAs)-rhenium(I)

Abstract

Keywords

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