TY - JOUR
T1 - Di-μchlorido-bis-[dichlorido-κbis(methyl-amido-κN) bis-(methyl-amine-κN)titanium(IV)]
AU - Thomas, Tegan
AU - Pugh, David
AU - Parkin, Ivan P.
AU - Carmalt, Claire J.
PY - 2011/7
Y1 - 2011/7
N2 - The title compound, [Ti2Cl6(C2H 6N)2(C2H7N)2], is a binuclear octa-hedral complex lying about an inversion centre. There are four different chloride environments, two terminal [Ti-Cl = 2.2847 (5) and 2.3371 (5) Å] and two bridging [Ti-Cl = 2.4414 (5) and 2.6759 (5) Å], with the Ti-Cl distances being strongly influenced by both the ligand trans to the chloride and whether or not the chloride anion is bridging between the two TiIV centres. The compound forms a two-dimensional network in the solid state, with weak inter-molecular C-H⋯Cl inter-actions giving rise to a planar network in the (10) plane.
AB - The title compound, [Ti2Cl6(C2H 6N)2(C2H7N)2], is a binuclear octa-hedral complex lying about an inversion centre. There are four different chloride environments, two terminal [Ti-Cl = 2.2847 (5) and 2.3371 (5) Å] and two bridging [Ti-Cl = 2.4414 (5) and 2.6759 (5) Å], with the Ti-Cl distances being strongly influenced by both the ligand trans to the chloride and whether or not the chloride anion is bridging between the two TiIV centres. The compound forms a two-dimensional network in the solid state, with weak inter-molecular C-H⋯Cl inter-actions giving rise to a planar network in the (10) plane.
UR - http://www.scopus.com/inward/record.url?scp=79959997888&partnerID=8YFLogxK
U2 - 10.1107/S0108270111023353
DO - 10.1107/S0108270111023353
M3 - Article
AN - SCOPUS:79959997888
SN - 0108-2701
VL - 67
SP - m234-m236
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 7
ER -