Dipyridyl β-diketonate complexes: Versatile polydentate metalloligands for metal-organic frameworks and hydrogen-bonded networks

Andrew D. Burrows; Christopher G. Frost; Mary F. Mahon; Paul R. Raithby; Catherine L. Renouf; Christopher Richardson; Anna J. Stevenson

doi:10.1039/c0cc00646g

Dipyridyl β-diketonate complexes: Versatile polydentate metalloligands for metal-organic frameworks and hydrogen-bonded networks

Andrew D. Burrows, Christopher G. Frost, Mary F. Mahon, Paul R. Raithby, Catherine L. Renouf, Christopher Richardson, Anna J. Stevenson

Chemistry

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

The Group 13 metal complexes [M(L²)₃], where M is Al or Ga and L² is 1,3-di(4-pyridyl)-1,3-propanedionato, are hexatopic metalloligands that have been used to prepare mixed-metal-organic frameworks containing interpenetrated primitive cubic networks. In contrast, the europium complex [Eu(HL²)₃(H₂L²)]Cl ₄·EtOH forms a hydrogen-bonded network following partial protonation of the pyridyl groups.

Original language	English
Pages (from-to)	5067-5069
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	28
DOIs	https://doi.org/10.1039/c0cc00646g
Publication status	Published - 28 Jul 2010

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title = "Dipyridyl β-diketonate complexes: Versatile polydentate metalloligands for metal-organic frameworks and hydrogen-bonded networks",

abstract = "The Group 13 metal complexes [M(L2)3], where M is Al or Ga and L2 is 1,3-di(4-pyridyl)-1,3-propanedionato, are hexatopic metalloligands that have been used to prepare mixed-metal-organic frameworks containing interpenetrated primitive cubic networks. In contrast, the europium complex [Eu(HL2)3(H2L2)]Cl 4·EtOH forms a hydrogen-bonded network following partial protonation of the pyridyl groups.",

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T2 - Versatile polydentate metalloligands for metal-organic frameworks and hydrogen-bonded networks

AU - Burrows, Andrew D.

AU - Frost, Christopher G.

AU - Mahon, Mary F.

AU - Raithby, Paul R.

AU - Renouf, Catherine L.

AU - Richardson, Christopher

AU - Stevenson, Anna J.

PY - 2010/7/28

Y1 - 2010/7/28

N2 - The Group 13 metal complexes [M(L2)3], where M is Al or Ga and L2 is 1,3-di(4-pyridyl)-1,3-propanedionato, are hexatopic metalloligands that have been used to prepare mixed-metal-organic frameworks containing interpenetrated primitive cubic networks. In contrast, the europium complex [Eu(HL2)3(H2L2)]Cl 4·EtOH forms a hydrogen-bonded network following partial protonation of the pyridyl groups.

AB - The Group 13 metal complexes [M(L2)3], where M is Al or Ga and L2 is 1,3-di(4-pyridyl)-1,3-propanedionato, are hexatopic metalloligands that have been used to prepare mixed-metal-organic frameworks containing interpenetrated primitive cubic networks. In contrast, the europium complex [Eu(HL2)3(H2L2)]Cl 4·EtOH forms a hydrogen-bonded network following partial protonation of the pyridyl groups.

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U2 - 10.1039/c0cc00646g

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JO - Chemical Communications

JF - Chemical Communications

IS - 28

ER -

Dipyridyl β-diketonate complexes: Versatile polydentate metalloligands for metal-organic frameworks and hydrogen-bonded networks

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