Fabrication and characterization of polymer composites for endodontic use

R. Alhashimi, F. Mannocci*, R. Foxton, S. Deb

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

Aim
To develop a low-density polyethylene-hydroxyapatite (HA-PE) composite with properties tailored to function as a potential root canal filling material.

Methodology
Hydroxyapatite and polyethylene mixed with strontium oxide as a radiopacifier were extruded from a single screw extruder fitted with an appropriate die to form fibres. The composition of the composite was optimized with clinical handling and placement in the canal being the prime consideration. The fibres were characterized using infrared spectroscopy (FTIR), and their thermal properties determined using differential scanning calorimetry (DSC). The tensile strength and elastic modulus of the composite fibres and gutta-percha were compared, dry and after 1month storage in simulated body fluid (SBF), using a universal testing machine. The radiopacity of the fibres was determined using digital radiography. The interaction of the composites with eugenol was evaluated and compared with gutta-percha. Data of the tensile test were submitted to two-way anova and Bonferroni tests (P<0.05).

Results
The endothermic peaks obtained from the DSC studies showed that the melting point of the HA/PE composites ranged between 110.5 and 111.2 degrees C, whereas gutta-percha exhibited a melting point at 52 degrees C. The tensile strength and elastic modulus of the silanated HA/PE composites were significantly higher than those of gutta-percha (P<0.0001) under dry conditions and 1month storage in SBF. The gutta-percha in eugenol showed a significant increase in the polymer molar mass, whereas the silanated HA/PE composites were unchanged. Radiological evaluations demonstrated that silanated HA/PE fibres were sufficiently radiopaque.

Conclusion
Promising materials for endodontic applications have been developed, offering relevant benefits over the traditional materials in terms of mechanical and chemical properties.

Original languageEnglish
Pages (from-to)574-582
Number of pages9
JournalInternational Endodontic Journal
Volume47
Issue number6
DOIs
Publication statusPublished - Jun 2014

Keywords

  • melt-extrusion
  • polyethylene-hydroxyapatite
  • root canal filling material
  • stiffness
  • tensile strength
  • REPLICATE CANAL IRREGULARITIES
  • PERCHA OBTURATION TECHNIQUES
  • GUTTA-PERCHA
  • FILLING MATERIAL
  • CORONAL MICROLEAKAGE
  • TREATED TEETH
  • EUGENOL
  • RESILON
  • BIOCOMPATIBILITY
  • HYDROXYAPATITE

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