Formation of ortho-cyano-aminothiophenolate ligands with versatile binding modes via facile carbon-sulfur bond cleavage of 2-aminobenzothiazoles at mercury(II) centres

Subhi A. Al-Jibori; Ahmed A. Irzoqi; Emad G H Al-Saraj; Ahmed S M Al-Janabi; Sucharita Basak-Modi; Shishir Ghosh; Kurt Merzweiler; Christoph Wagner; Harry Schmidt; Graeme Hogarth

doi:10.1039/c5dt02080h

Formation of ortho-cyano-aminothiophenolate ligands with versatile binding modes via facile carbon-sulfur bond cleavage of 2-aminobenzothiazoles at mercury(II) centres

Subhi A. Al-Jibori^*, Ahmed A. Irzoqi, Emad G H Al-Saraj, Ahmed S M Al-Janabi, Sucharita Basak-Modi, Shishir Ghosh, Kurt Merzweiler, Christoph Wagner, Harry Schmidt, Graeme Hogarth

^*Corresponding author for this work

Chemistry

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Abstract

Addition of 2-aminobenzothiazole and substituted derivatives to mercuric acetate in warm ethanol leads to the high yield formation of [Hg{SC₆H₃XN(CN)}]_n resulting from loss of hydrogen and sulfur-carbon bond cleavage. Addition of phosphines affords a series of complexes in which the new ortho-cyano-aminothiophenolate ligands adopt three different binding modes.

Original language	English
Pages (from-to)	14217-14219
Number of pages	3
Journal	Dalton transactions (Cambridge, England : 2003)
Volume	44
Issue number	32
DOIs	https://doi.org/10.1039/c5dt02080h
Publication status	Published - 28 Aug 2015

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Formation of ortho-cyano-aminothiophenolate ligands_AL-JIBORI_Published28August2015_GREEN AAMSubmitted manuscript, 398 KB

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Al-Jibori, S. A., Irzoqi, A. A., Al-Saraj, E. G. H., Al-Janabi, A. S. M., Basak-Modi, S., Ghosh, S., Merzweiler, K., Wagner, C., Schmidt, H., & Hogarth, G. (2015). Formation of ortho-cyano-aminothiophenolate ligands with versatile binding modes via facile carbon-sulfur bond cleavage of 2-aminobenzothiazoles at mercury(II) centres. Dalton transactions (Cambridge, England : 2003), 44(32), 14217-14219. https://doi.org/10.1039/c5dt02080h

@article{b837bb5624334051814d140b9be73141,

title = "Formation of ortho-cyano-aminothiophenolate ligands with versatile binding modes via facile carbon-sulfur bond cleavage of 2-aminobenzothiazoles at mercury(II) centres",

abstract = "Addition of 2-aminobenzothiazole and substituted derivatives to mercuric acetate in warm ethanol leads to the high yield formation of [Hg{SC6H3XN(CN)}]n resulting from loss of hydrogen and sulfur-carbon bond cleavage. Addition of phosphines affords a series of complexes in which the new ortho-cyano-aminothiophenolate ligands adopt three different binding modes.",

author = "Al-Jibori, {Subhi A.} and Irzoqi, {Ahmed A.} and Al-Saraj, {Emad G H} and Al-Janabi, {Ahmed S M} and Sucharita Basak-Modi and Shishir Ghosh and Kurt Merzweiler and Christoph Wagner and Harry Schmidt and Graeme Hogarth",

year = "2015",

month = aug,

day = "28",

doi = "10.1039/c5dt02080h",

language = "English",

volume = "44",

pages = "14217--14219",

journal = "Dalton transactions (Cambridge, England : 2003)",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "32",

}

Al-Jibori, SA, Irzoqi, AA, Al-Saraj, EGH, Al-Janabi, ASM, Basak-Modi, S, Ghosh, S, Merzweiler, K, Wagner, C, Schmidt, H & Hogarth, G 2015, 'Formation of ortho-cyano-aminothiophenolate ligands with versatile binding modes via facile carbon-sulfur bond cleavage of 2-aminobenzothiazoles at mercury(II) centres', Dalton transactions (Cambridge, England : 2003), vol. 44, no. 32, pp. 14217-14219. https://doi.org/10.1039/c5dt02080h

Formation of ortho-cyano-aminothiophenolate ligands with versatile binding modes via facile carbon-sulfur bond cleavage of 2-aminobenzothiazoles at mercury(II) centres. / Al-Jibori, Subhi A.; Irzoqi, Ahmed A.; Al-Saraj, Emad G H et al.
In: Dalton transactions (Cambridge, England : 2003), Vol. 44, No. 32, 28.08.2015, p. 14217-14219.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Formation of ortho-cyano-aminothiophenolate ligands with versatile binding modes via facile carbon-sulfur bond cleavage of 2-aminobenzothiazoles at mercury(II) centres

AU - Al-Jibori, Subhi A.

AU - Irzoqi, Ahmed A.

AU - Al-Saraj, Emad G H

AU - Al-Janabi, Ahmed S M

AU - Basak-Modi, Sucharita

AU - Ghosh, Shishir

AU - Merzweiler, Kurt

AU - Wagner, Christoph

AU - Schmidt, Harry

AU - Hogarth, Graeme

PY - 2015/8/28

Y1 - 2015/8/28

N2 - Addition of 2-aminobenzothiazole and substituted derivatives to mercuric acetate in warm ethanol leads to the high yield formation of [Hg{SC6H3XN(CN)}]n resulting from loss of hydrogen and sulfur-carbon bond cleavage. Addition of phosphines affords a series of complexes in which the new ortho-cyano-aminothiophenolate ligands adopt three different binding modes.

AB - Addition of 2-aminobenzothiazole and substituted derivatives to mercuric acetate in warm ethanol leads to the high yield formation of [Hg{SC6H3XN(CN)}]n resulting from loss of hydrogen and sulfur-carbon bond cleavage. Addition of phosphines affords a series of complexes in which the new ortho-cyano-aminothiophenolate ligands adopt three different binding modes.

UR - http://www.scopus.com/inward/record.url?scp=84938884873&partnerID=8YFLogxK

U2 - 10.1039/c5dt02080h

DO - 10.1039/c5dt02080h

M3 - Article

C2 - 26216202

AN - SCOPUS:84938884873

SN - 1477-9226

VL - 44

SP - 14217

EP - 14219

JO - Dalton transactions (Cambridge, England : 2003)

JF - Dalton transactions (Cambridge, England : 2003)

IS - 32

ER -

Formation of ortho-cyano-aminothiophenolate ligands with versatile binding modes via facile carbon-sulfur bond cleavage of 2-aminobenzothiazoles at mercury(II) centres

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