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Formation of ortho-cyano-aminothiophenolate ligands with versatile binding modes via facile carbon-sulfur bond cleavage of 2-aminobenzothiazoles at mercury(II) centres

Research output: Contribution to journalArticle

Subhi A. Al-Jibori, Ahmed A. Irzoqi, Emad G H Al-Saraj, Ahmed S M Al-Janabi, Sucharita Basak-Modi, Shishir Ghosh, Kurt Merzweiler, Christoph Wagner, Harry Schmidt, Graeme Hogarth

Original languageEnglish
Pages (from-to)14217-14219
Number of pages3
JournalDalton transactions (Cambridge, England : 2003)
Volume44
Issue number32
DOIs
Publication statusPublished - 28 Aug 2015

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Abstract

Addition of 2-aminobenzothiazole and substituted derivatives to mercuric acetate in warm ethanol leads to the high yield formation of [Hg{SC6H3XN(CN)}]n resulting from loss of hydrogen and sulfur-carbon bond cleavage. Addition of phosphines affords a series of complexes in which the new ortho-cyano-aminothiophenolate ligands adopt three different binding modes.

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