Hydrogenase biomimetics: Fe-2(CO)(4)(mu-dppf)(mu-pdt) (dppf=1,1 '-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst

Shishir Ghosh; Graeme Hogarth; Nathan Hollingsworth; Katherine B. Holt; Shariff E. Kabir; Ben E. Sanchez

doi:10.1039/c3cc46456c

Hydrogenase biomimetics: Fe-2(CO)(4)(mu-dppf)(mu-pdt) (dppf=1,1 '-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst

Shishir Ghosh, Graeme Hogarth^*, Nathan Hollingsworth, Katherine B. Holt, Shariff E. Kabir, Ben E. Sanchez

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

111 Citations (Scopus)

Abstract

Fe-2(CO)(4)(mu-dppf)(mu-pdt) catalyses the conversion of protons and electrons into hydrogen and also the reverse reaction thus mimicing both types of binuclear hydrogenase enzymes.

Original language	English
Pages (from-to)	945-947
Number of pages	3
Journal	CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRY
Volume	50
Issue number	8
DOIs	https://doi.org/10.1039/c3cc46456c
Publication status	Published - Jan 2014

Keywords

IRON-ONLY HYDROGENASE
ACTIVE-SITE
CRYSTAL-STRUCTURE
1,1-BIS(DIPHENYLPHOSPHINO)FERROCENE DPPF
HETEROPOLYMETALLIC COMPLEXES
STRUCTURAL-CHARACTERIZATION
PHOSPHINE LIGAND
FE-HYDROGENASE
H-2 EVOLUTION
MODELS

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10.1039/c3cc46456c

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@article{bb0844f0bd034c559f4217fe9606b885,

title = "Hydrogenase biomimetics: Fe-2(CO)(4)(mu-dppf)(mu-pdt) (dppf=1,1 '-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst",

abstract = "Fe-2(CO)(4)(mu-dppf)(mu-pdt) catalyses the conversion of protons and electrons into hydrogen and also the reverse reaction thus mimicing both types of binuclear hydrogenase enzymes.",

keywords = "IRON-ONLY HYDROGENASE, ACTIVE-SITE, CRYSTAL-STRUCTURE, 1,1-BIS(DIPHENYLPHOSPHINO)FERROCENE DPPF, HETEROPOLYMETALLIC COMPLEXES, STRUCTURAL-CHARACTERIZATION, PHOSPHINE LIGAND, FE-HYDROGENASE, H-2 EVOLUTION, MODELS",

author = "Shishir Ghosh and Graeme Hogarth and Nathan Hollingsworth and Holt, {Katherine B.} and Kabir, {Shariff E.} and Sanchez, {Ben E.}",

year = "2014",

month = jan,

doi = "10.1039/c3cc46456c",

language = "English",

volume = "50",

pages = "945--947",

journal = "CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRY",

issn = "1359-7345",

publisher = "ROYAL SOC CHEMISTRY",

number = "8",

}

Hydrogenase biomimetics: Fe-2(CO)(4)(mu-dppf)(mu-pdt) (dppf=1,1 '-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst. / Ghosh, Shishir; Hogarth, Graeme; Hollingsworth, Nathan et al.
In: CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRY, Vol. 50, No. 8, 01.2014, p. 945-947.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Hydrogenase biomimetics

T2 - Fe-2(CO)(4)(mu-dppf)(mu-pdt) (dppf=1,1 '-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst

AU - Ghosh, Shishir

AU - Hogarth, Graeme

AU - Hollingsworth, Nathan

AU - Holt, Katherine B.

AU - Kabir, Shariff E.

AU - Sanchez, Ben E.

PY - 2014/1

Y1 - 2014/1

N2 - Fe-2(CO)(4)(mu-dppf)(mu-pdt) catalyses the conversion of protons and electrons into hydrogen and also the reverse reaction thus mimicing both types of binuclear hydrogenase enzymes.

AB - Fe-2(CO)(4)(mu-dppf)(mu-pdt) catalyses the conversion of protons and electrons into hydrogen and also the reverse reaction thus mimicing both types of binuclear hydrogenase enzymes.

KW - IRON-ONLY HYDROGENASE

KW - ACTIVE-SITE

KW - CRYSTAL-STRUCTURE

KW - 1,1-BIS(DIPHENYLPHOSPHINO)FERROCENE DPPF

KW - HETEROPOLYMETALLIC COMPLEXES

KW - STRUCTURAL-CHARACTERIZATION

KW - PHOSPHINE LIGAND

KW - FE-HYDROGENASE

KW - H-2 EVOLUTION

KW - MODELS

U2 - 10.1039/c3cc46456c

DO - 10.1039/c3cc46456c

M3 - Article

SN - 1359-7345

VL - 50

SP - 945

EP - 947

JO - CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRY

JF - CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRY

IS - 8

ER -

Hydrogenase biomimetics: Fe-2(CO)(4)(mu-dppf)(mu-pdt) (dppf=1,1 '-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst

Abstract

Keywords

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