Interplay between core and peripheral chirality in polyethers

TY - JOUR

T1 - Interplay between core and peripheral chirality in polyethers

AU - Brewer, A R E

AU - Drake, A F

AU - Gibson, S E

AU - Rendell, J T

PY - 2007/8/30

Y1 - 2007/8/30

N2 - A chiral-base mediated reaction has been used to synthesise the polyethers illustrated and their enantiomers; CD spectroscopy revealed that the homochiral isomers A may be viewed as a C-3-symmetric arrangement of fixed paddles while the heterochiral isomers B form a C-3-symmetric arrangement of rotating paddles

AB - A chiral-base mediated reaction has been used to synthesise the polyethers illustrated and their enantiomers; CD spectroscopy revealed that the homochiral isomers A may be viewed as a C-3-symmetric arrangement of fixed paddles while the heterochiral isomers B form a C-3-symmetric arrangement of rotating paddles

U2 - 10.1021/ol070934t

DO - 10.1021/ol070934t

M3 - Article

SN - 1523-7052

VL - 9

SP - 3487

EP - 3490

JO - ORGANIC LETTERS

JF - ORGANIC LETTERS

IS - 18

ER -