Monitoring potassium metal electrodeposition from an ionic liquid using in situ electrochemical-X-ray photoelectron spectroscopy

Rahmat Wibowo; Leigh Aldous; Robert M. J. Jacobs; Ninie S. A. Manan; Richard G. Compton

doi:10.1016/j.cplett.2011.04.071

Monitoring potassium metal electrodeposition from an ionic liquid using in situ electrochemical-X-ray photoelectron spectroscopy

Rahmat Wibowo, Leigh Aldous, Robert M. J. Jacobs, Ninie S. A. Manan, Richard G. Compton

Chemistry

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

The real time electrodeposition of potassium has been monitored for the first time in an ionic liquid using in situ electrodeposition-X-ray photoelectron spectroscopy (XPS). The ionic liquid used was N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C4mpyrr][NTf2]), and electrodeposition occurred at a nickel mesh electrode. Potassium electrochemistry was monitored at the ionic liquid–vacuum–electrode interface using a novel cell design.

Original language	English
Pages (from-to)	72-76
Journal	CHEMICAL PHYSICS LETTERS
Volume	509
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cplett.2011.04.071
Publication status	Published - 3 Jun 2011

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10.1016/j.cplett.2011.04.071

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title = "Monitoring potassium metal electrodeposition from an ionic liquid using in situ electrochemical-X-ray photoelectron spectroscopy",

abstract = "The real time electrodeposition of potassium has been monitored for the first time in an ionic liquid using in situ electrodeposition-X-ray photoelectron spectroscopy (XPS). The ionic liquid used was N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C4mpyrr][NTf2]), and electrodeposition occurred at a nickel mesh electrode. Potassium electrochemistry was monitored at the ionic liquid–vacuum–electrode interface using a novel cell design.",

author = "Rahmat Wibowo and Leigh Aldous and Jacobs, {Robert M. J.} and Manan, {Ninie S. A.} and Compton, {Richard G.}",

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doi = "10.1016/j.cplett.2011.04.071",

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T1 - Monitoring potassium metal electrodeposition from an ionic liquid using in situ electrochemical-X-ray photoelectron spectroscopy

AU - Wibowo, Rahmat

AU - Aldous, Leigh

AU - Jacobs, Robert M. J.

AU - Manan, Ninie S. A.

AU - Compton, Richard G.

PY - 2011/6/3

Y1 - 2011/6/3

N2 - The real time electrodeposition of potassium has been monitored for the first time in an ionic liquid using in situ electrodeposition-X-ray photoelectron spectroscopy (XPS). The ionic liquid used was N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C4mpyrr][NTf2]), and electrodeposition occurred at a nickel mesh electrode. Potassium electrochemistry was monitored at the ionic liquid–vacuum–electrode interface using a novel cell design.

AB - The real time electrodeposition of potassium has been monitored for the first time in an ionic liquid using in situ electrodeposition-X-ray photoelectron spectroscopy (XPS). The ionic liquid used was N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C4mpyrr][NTf2]), and electrodeposition occurred at a nickel mesh electrode. Potassium electrochemistry was monitored at the ionic liquid–vacuum–electrode interface using a novel cell design.

U2 - 10.1016/j.cplett.2011.04.071

DO - 10.1016/j.cplett.2011.04.071

M3 - Article

SN - 0009-2614

VL - 509

SP - 72

EP - 76

JO - CHEMICAL PHYSICS LETTERS

JF - CHEMICAL PHYSICS LETTERS

IS - 1-3

ER -

Monitoring potassium metal electrodeposition from an ionic liquid using in situ electrochemical-X-ray photoelectron spectroscopy

Abstract

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