N-14 electric field gradient in trimethylamine complexes as a diagnostic for formation of ion pairs

C Domene; PW Fowler; AC Legon

doi:10.1016/S0009-2614(99)00736-8

N-14 electric field gradient in trimethylamine complexes as a diagnostic for formation of ion pairs

C Domene, PW Fowler^*, AC Legon

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Electric field gradients at N and Cl nuclei are calculated as functions of separation in ion-pair and neutral-monomer models of(CH3)(3)N/F-2 and (CH3)(3)N/ClF. Comparison of the predictions with the previously measured nuclear quadrupole coupling constants for these complexes supports the attribution of significant ion-pair character to both species. (C) 1999 Elsevier Science B.V. All rights reserved.

Original language	English
Pages (from-to)	463-470
Number of pages	8
Journal	CHEMICAL PHYSICS LETTERS
Volume	309
Issue number	5-6
DOIs	https://doi.org/10.1016/S0009-2614(99)00736-8
Publication status	Published - 20 Aug 1999

Keywords

ROTATIONAL SPECTROSCOPY
GAS-PHASE
IDENTIFICATION
MIXTURES
CIF

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10.1016/S0009-2614(99)00736-8

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title = "N-14 electric field gradient in trimethylamine complexes as a diagnostic for formation of ion pairs",

abstract = "Electric field gradients at N and Cl nuclei are calculated as functions of separation in ion-pair and neutral-monomer models of(CH3)(3)N/F-2 and (CH3)(3)N/ClF. Comparison of the predictions with the previously measured nuclear quadrupole coupling constants for these complexes supports the attribution of significant ion-pair character to both species. (C) 1999 Elsevier Science B.V. All rights reserved.",

keywords = "ROTATIONAL SPECTROSCOPY, GAS-PHASE, IDENTIFICATION, MIXTURES, CIF",

author = "C Domene and PW Fowler and AC Legon",

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doi = "10.1016/S0009-2614(99)00736-8",

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T1 - N-14 electric field gradient in trimethylamine complexes as a diagnostic for formation of ion pairs

AU - Domene, C

AU - Fowler, PW

AU - Legon, AC

PY - 1999/8/20

Y1 - 1999/8/20

N2 - Electric field gradients at N and Cl nuclei are calculated as functions of separation in ion-pair and neutral-monomer models of(CH3)(3)N/F-2 and (CH3)(3)N/ClF. Comparison of the predictions with the previously measured nuclear quadrupole coupling constants for these complexes supports the attribution of significant ion-pair character to both species. (C) 1999 Elsevier Science B.V. All rights reserved.

AB - Electric field gradients at N and Cl nuclei are calculated as functions of separation in ion-pair and neutral-monomer models of(CH3)(3)N/F-2 and (CH3)(3)N/ClF. Comparison of the predictions with the previously measured nuclear quadrupole coupling constants for these complexes supports the attribution of significant ion-pair character to both species. (C) 1999 Elsevier Science B.V. All rights reserved.

KW - ROTATIONAL SPECTROSCOPY

KW - GAS-PHASE

KW - IDENTIFICATION

KW - MIXTURES

KW - CIF

U2 - 10.1016/S0009-2614(99)00736-8

DO - 10.1016/S0009-2614(99)00736-8

M3 - Article

SN - 0009-2614

VL - 309

SP - 463

EP - 470

JO - CHEMICAL PHYSICS LETTERS

JF - CHEMICAL PHYSICS LETTERS

IS - 5-6

ER -

N-14 electric field gradient in trimethylamine complexes as a diagnostic for formation of ion pairs

Abstract

Keywords

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