Neutral fac-[Re(NNN)(CO)3] complexes with NNN tridentate ligands containing pyrrole or indole

Antonio Shegani; Charalampos Triantis; Christos Kiritsis; Catherine Raptopoulou; Vassilis Psycharis; Maria Pelecanou; Ioannis Pirmettis; Minas Papadopoulos

doi:10.1016/j.inoche.2015.11.002

Neutral fac-[Re(NNN)(CO)₃] complexes with NNN tridentate ligands containing pyrrole or indole

Antonio Shegani, Charalampos Triantis, Christos Kiritsis, Catherine Raptopoulou, Vassilis Psycharis, Maria Pelecanou, Ioannis Pirmettis, Minas Papadopoulos^*

^*Corresponding author for this work

Imaging Chemistry & Biology

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

New neutral fac-ReNNN(CO)₃ complexes where NNN are the Schiff base tridentate ligands N-(1H-pyrrol-2-ylmethylene)-2-(pyridin-2-yl)ethanamine (complex 1) and N-(1H-indol-2-ylmethylene)-2-(pyridin-2-yl)ethanamine (complex 2) were synthesized and characterized by elemental analyses, infrared and ¹H and ¹³C NMR spectroscopies. The molecular structure of complex 1 was confirmed by X-ray crystallographic analysis that revealed a distorted octahedral geometry around Re.

Original language	English
Pages (from-to)	1-4
Number of pages	4
Journal	INORGANIC CHEMISTRY COMMUNICATIONS
Volume	63
DOIs	https://doi.org/10.1016/j.inoche.2015.11.002
Publication status	Published - Jan 2016

Keywords

Indole
Pyrrole
Rhenium(I)
Tricarbonyl
X-ray structure

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10.1016/j.inoche.2015.11.002

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title = "Neutral fac-[Re(NNN)(CO)3] complexes with NNN tridentate ligands containing pyrrole or indole",

abstract = "New neutral fac-ReNNN(CO)3 complexes where NNN are the Schiff base tridentate ligands N-(1H-pyrrol-2-ylmethylene)-2-(pyridin-2-yl)ethanamine (complex 1) and N-(1H-indol-2-ylmethylene)-2-(pyridin-2-yl)ethanamine (complex 2) were synthesized and characterized by elemental analyses, infrared and 1H and 13C NMR spectroscopies. The molecular structure of complex 1 was confirmed by X-ray crystallographic analysis that revealed a distorted octahedral geometry around Re.",

keywords = "Indole, Pyrrole, Rhenium(I), Tricarbonyl, X-ray structure",

author = "Antonio Shegani and Charalampos Triantis and Christos Kiritsis and Catherine Raptopoulou and Vassilis Psycharis and Maria Pelecanou and Ioannis Pirmettis and Minas Papadopoulos",

year = "2016",

month = jan,

doi = "10.1016/j.inoche.2015.11.002",

language = "English",

volume = "63",

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TY - JOUR

T1 - Neutral fac-[Re(NNN)(CO)3] complexes with NNN tridentate ligands containing pyrrole or indole

AU - Shegani, Antonio

AU - Triantis, Charalampos

AU - Kiritsis, Christos

AU - Raptopoulou, Catherine

AU - Psycharis, Vassilis

AU - Pelecanou, Maria

AU - Pirmettis, Ioannis

AU - Papadopoulos, Minas

PY - 2016/1

Y1 - 2016/1

N2 - New neutral fac-ReNNN(CO)3 complexes where NNN are the Schiff base tridentate ligands N-(1H-pyrrol-2-ylmethylene)-2-(pyridin-2-yl)ethanamine (complex 1) and N-(1H-indol-2-ylmethylene)-2-(pyridin-2-yl)ethanamine (complex 2) were synthesized and characterized by elemental analyses, infrared and 1H and 13C NMR spectroscopies. The molecular structure of complex 1 was confirmed by X-ray crystallographic analysis that revealed a distorted octahedral geometry around Re.

AB - New neutral fac-ReNNN(CO)3 complexes where NNN are the Schiff base tridentate ligands N-(1H-pyrrol-2-ylmethylene)-2-(pyridin-2-yl)ethanamine (complex 1) and N-(1H-indol-2-ylmethylene)-2-(pyridin-2-yl)ethanamine (complex 2) were synthesized and characterized by elemental analyses, infrared and 1H and 13C NMR spectroscopies. The molecular structure of complex 1 was confirmed by X-ray crystallographic analysis that revealed a distorted octahedral geometry around Re.

KW - Indole

KW - Pyrrole

KW - Rhenium(I)

KW - Tricarbonyl

KW - X-ray structure

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U2 - 10.1016/j.inoche.2015.11.002

DO - 10.1016/j.inoche.2015.11.002

M3 - Article

AN - SCOPUS:84948458802

SN - 1387-7003

VL - 63

SP - 1

EP - 4

JO - INORGANIC CHEMISTRY COMMUNICATIONS

JF - INORGANIC CHEMISTRY COMMUNICATIONS

ER -

Neutral fac-[Re(NNN)(CO)₃] complexes with NNN tridentate ligands containing pyrrole or indole

Abstract

Keywords

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