Palladium(II) saccharinate complexes trans-[Pd(sac)2(LH)2] with amino- and acetylamino-pyridine co-ligands: molecular structures of trans-[PdCl2(2-ampyH)2].2dmf (2-ampyH = 2-amino-3-methylpyridine) and trans-[Pd(κ2-2-acmpy)2] (2-acmpyH = 2-acetylamino-3-methylpyridine)

Subhi A. Al-jibori; Rawaa A. Q. Al-nassiry; Ghassan H. H. Al-jibori; Kurt Merzweiler; Christoph Wagner; Harry Schmidt; Sucharita Basak-modi; Graeme Hogarth

doi:10.1007/s11243-014-9845-6

Palladium(II) saccharinate complexes trans-[Pd(sac)2(LH)2] with amino- and acetylamino-pyridine co-ligands: molecular structures of trans-[PdCl2(2-ampyH)2].2dmf (2-ampyH = 2-amino-3-methylpyridine) and trans-[Pd(κ2-2-acmpy)2] (2-acmpyH = 2-acetylamino-3-methylpyridine)

Subhi A. Al-jibori, Rawaa A. Q. Al-nassiry, Ghassan H. H. Al-jibori, Kurt Merzweiler, Christoph Wagner, Harry Schmidt, Sucharita Basak-modi, Graeme Hogarth

Chemistry

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Reaction of Na2[PdCl4] with two equivalents of amino- or acetylamino-pyridines (LH) affords trans-[PdCl2-(LH)2] {LH = 2-amino-3-methylpyridine (2-ampyH), 3-aminopyridine (3-apyH), 2-acetylamino-3-methylpyridine (2-acmpyH), 3-acetylamino-pyridine (3-acpyH)}. An X-ray crystal structure of trans-[PdCl2(2-ampyH)2] shows that the 2-ampy-H ligands are coordinated in a monodentate fashion via the nitrogen atoms of the pyridine rings. Treatment of trans-[PdCl2(2-acmpyH)2] with NEt3 affords the cyclometalated complex, trans-[Pd(κ2-2-acmpy)2], the X-ray structure of which shows that the 2-acmpy ligand is coordinated to palladium in a bidentate fashion via the nitrogen atom of the pyridine ring and oxygen. Reaction of trans-[PdCl2(LH)2] with two equivalents of sodium saccharinate affords the bis(saccharinate) complexes, trans-[Pd(sac)2(LH)2], in which the saccharinate anions are coordinated via the amide nitrogen atom.

Original language	English
Pages (from-to)	735-740
Number of pages	6
Journal	Transition Metal Chemistry
Volume	39
Issue number	7
DOIs	https://doi.org/10.1007/s11243-014-9845-6
Publication status	Published - 1 Oct 2014

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Al-jibori, S. A., Al-nassiry, R. A. Q., Al-jibori, G. H. H., Merzweiler, K., Wagner, C., Schmidt, H., Basak-modi, S., & Hogarth, G. (2014). Palladium(II) saccharinate complexes trans-[Pd(sac)2(LH)2] with amino- and acetylamino-pyridine co-ligands: molecular structures of trans-[PdCl2(2-ampyH)2].2dmf (2-ampyH = 2-amino-3-methylpyridine) and trans-[Pd(κ2-2-acmpy)2] (2-acmpyH = 2-acetylamino-3-methylpyridine). Transition Metal Chemistry, 39(7), 735-740. https://doi.org/10.1007/s11243-014-9845-6

Al-jibori, Subhi A. ; Al-nassiry, Rawaa A. Q. ; Al-jibori, Ghassan H. H. et al. / Palladium(II) saccharinate complexes trans-[Pd(sac)2(LH)2] with amino- and acetylamino-pyridine co-ligands : molecular structures of trans-[PdCl2(2-ampyH)2].2dmf (2-ampyH = 2-amino-3-methylpyridine) and trans-[Pd(κ2-2-acmpy)2] (2-acmpyH = 2-acetylamino-3-methylpyridine). In: Transition Metal Chemistry. 2014 ; Vol. 39, No. 7. pp. 735-740.

@article{b6a53f1bb68f4fa390eb3b685c1ef285,

title = "Palladium(II) saccharinate complexes trans-[Pd(sac)2(LH)2] with amino- and acetylamino-pyridine co-ligands: molecular structures of trans-[PdCl2(2-ampyH)2].2dmf (2-ampyH = 2-amino-3-methylpyridine) and trans-[Pd(κ2-2-acmpy)2] (2-acmpyH = 2-acetylamino-3-methylpyridine)",

abstract = "Reaction of Na2[PdCl4] with two equivalents of amino- or acetylamino-pyridines (LH) affords trans-[PdCl2-(LH)2] {LH = 2-amino-3-methylpyridine (2-ampyH), 3-aminopyridine (3-apyH), 2-acetylamino-3-methylpyridine (2-acmpyH), 3-acetylamino-pyridine (3-acpyH)}. An X-ray crystal structure of trans-[PdCl2(2-ampyH)2] shows that the 2-ampy-H ligands are coordinated in a monodentate fashion via the nitrogen atoms of the pyridine rings. Treatment of trans-[PdCl2(2-acmpyH)2] with NEt3 affords the cyclometalated complex, trans-[Pd(κ2-2-acmpy)2], the X-ray structure of which shows that the 2-acmpy ligand is coordinated to palladium in a bidentate fashion via the nitrogen atom of the pyridine ring and oxygen. Reaction of trans-[PdCl2(LH)2] with two equivalents of sodium saccharinate affords the bis(saccharinate) complexes, trans-[Pd(sac)2(LH)2], in which the saccharinate anions are coordinated via the amide nitrogen atom.",

author = "Al-jibori, {Subhi A.} and Al-nassiry, {Rawaa A. Q.} and Al-jibori, {Ghassan H. H.} and Kurt Merzweiler and Christoph Wagner and Harry Schmidt and Sucharita Basak-modi and Graeme Hogarth",

year = "2014",

month = oct,

day = "1",

doi = "10.1007/s11243-014-9845-6",

language = "English",

volume = "39",

pages = "735--740",

journal = "Transition Metal Chemistry",

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Al-jibori, SA, Al-nassiry, RAQ, Al-jibori, GHH, Merzweiler, K, Wagner, C, Schmidt, H, Basak-modi, S & Hogarth, G 2014, 'Palladium(II) saccharinate complexes trans-[Pd(sac)2(LH)2] with amino- and acetylamino-pyridine co-ligands: molecular structures of trans-[PdCl2(2-ampyH)2].2dmf (2-ampyH = 2-amino-3-methylpyridine) and trans-[Pd(κ2-2-acmpy)2] (2-acmpyH = 2-acetylamino-3-methylpyridine)', Transition Metal Chemistry, vol. 39, no. 7, pp. 735-740. https://doi.org/10.1007/s11243-014-9845-6

Palladium(II) saccharinate complexes trans-[Pd(sac)2(LH)2] with amino- and acetylamino-pyridine co-ligands: molecular structures of trans-[PdCl2(2-ampyH)2].2dmf (2-ampyH = 2-amino-3-methylpyridine) and trans-[Pd(κ2-2-acmpy)2] (2-acmpyH = 2-acetylamino-3-methylpyridine). / Al-jibori, Subhi A.; Al-nassiry, Rawaa A. Q.; Al-jibori, Ghassan H. H. et al.
In: Transition Metal Chemistry, Vol. 39, No. 7, 01.10.2014, p. 735-740.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Palladium(II) saccharinate complexes trans-[Pd(sac)2(LH)2] with amino- and acetylamino-pyridine co-ligands

T2 - molecular structures of trans-[PdCl2(2-ampyH)2].2dmf (2-ampyH = 2-amino-3-methylpyridine) and trans-[Pd(κ2-2-acmpy)2] (2-acmpyH = 2-acetylamino-3-methylpyridine)

AU - Al-jibori, Subhi A.

AU - Al-nassiry, Rawaa A. Q.

AU - Al-jibori, Ghassan H. H.

AU - Merzweiler, Kurt

AU - Wagner, Christoph

AU - Schmidt, Harry

AU - Basak-modi, Sucharita

AU - Hogarth, Graeme

PY - 2014/10/1

Y1 - 2014/10/1

N2 - Reaction of Na2[PdCl4] with two equivalents of amino- or acetylamino-pyridines (LH) affords trans-[PdCl2-(LH)2] {LH = 2-amino-3-methylpyridine (2-ampyH), 3-aminopyridine (3-apyH), 2-acetylamino-3-methylpyridine (2-acmpyH), 3-acetylamino-pyridine (3-acpyH)}. An X-ray crystal structure of trans-[PdCl2(2-ampyH)2] shows that the 2-ampy-H ligands are coordinated in a monodentate fashion via the nitrogen atoms of the pyridine rings. Treatment of trans-[PdCl2(2-acmpyH)2] with NEt3 affords the cyclometalated complex, trans-[Pd(κ2-2-acmpy)2], the X-ray structure of which shows that the 2-acmpy ligand is coordinated to palladium in a bidentate fashion via the nitrogen atom of the pyridine ring and oxygen. Reaction of trans-[PdCl2(LH)2] with two equivalents of sodium saccharinate affords the bis(saccharinate) complexes, trans-[Pd(sac)2(LH)2], in which the saccharinate anions are coordinated via the amide nitrogen atom.

AB - Reaction of Na2[PdCl4] with two equivalents of amino- or acetylamino-pyridines (LH) affords trans-[PdCl2-(LH)2] {LH = 2-amino-3-methylpyridine (2-ampyH), 3-aminopyridine (3-apyH), 2-acetylamino-3-methylpyridine (2-acmpyH), 3-acetylamino-pyridine (3-acpyH)}. An X-ray crystal structure of trans-[PdCl2(2-ampyH)2] shows that the 2-ampy-H ligands are coordinated in a monodentate fashion via the nitrogen atoms of the pyridine rings. Treatment of trans-[PdCl2(2-acmpyH)2] with NEt3 affords the cyclometalated complex, trans-[Pd(κ2-2-acmpy)2], the X-ray structure of which shows that the 2-acmpy ligand is coordinated to palladium in a bidentate fashion via the nitrogen atom of the pyridine ring and oxygen. Reaction of trans-[PdCl2(LH)2] with two equivalents of sodium saccharinate affords the bis(saccharinate) complexes, trans-[Pd(sac)2(LH)2], in which the saccharinate anions are coordinated via the amide nitrogen atom.

U2 - 10.1007/s11243-014-9845-6

DO - 10.1007/s11243-014-9845-6

M3 - Article

SN - 0340-4285

VL - 39

SP - 735

EP - 740

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 7

ER -

Al-jibori SA, Al-nassiry RAQ, Al-jibori GHH, Merzweiler K, Wagner C, Schmidt H et al. Palladium(II) saccharinate complexes trans-[Pd(sac)2(LH)2] with amino- and acetylamino-pyridine co-ligands: molecular structures of trans-[PdCl2(2-ampyH)2].2dmf (2-ampyH = 2-amino-3-methylpyridine) and trans-[Pd(κ2-2-acmpy)2] (2-acmpyH = 2-acetylamino-3-methylpyridine). Transition Metal Chemistry. 2014 Oct 1;39(7):735-740. doi: 10.1007/s11243-014-9845-6