Palladium(II) saccharinate (sac) and thiosaccharinate (tsac) complexes with supporting amino- and acetylamino-thiazole ligands: Crystal structures of trans-[PdCl2(abzt)2]·dmf (abzt = 2-aminobenzothiazole), trans-[PdCl2(bzta)2].dmf (bzta = 2-acetylaminobenzothiazole) and trans-[Pd(sac)2(abzt)2]·2dmf

Subhi A. Al-jibori; Adnan T. Habeeb; Ghassan H.h. Al-jibori; Noor A. Dayaaf; Kurt Merzweiler; Christoph Wagner; Harry Schmidt; Graeme Hogarth

doi:10.1016/j.poly.2013.09.007

Palladium(II) saccharinate (sac) and thiosaccharinate (tsac) complexes with supporting amino- and acetylamino-thiazole ligands: Crystal structures of trans-[PdCl2(abzt)2]·dmf (abzt = 2-aminobenzothiazole), trans-[PdCl2(bzta)2].dmf (bzta = 2-acetylaminobenzothiazole) and trans-[Pd(sac)2(abzt)2]·2dmf

Subhi A. Al-jibori, Adnan T. Habeeb, Ghassan H.h. Al-jibori, Noor A. Dayaaf, Kurt Merzweiler, Christoph Wagner, Harry Schmidt, Graeme Hogarth

Chemistry

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Treatment of Na2PdCl4 with two equivalents of amino- or acetylamino-thiazoles [L = 2-aminobenzothiazole (abzt), 2-aminothiazole (atz), 2-acetylaminobenzothiazole (bzta) and 2-acetylaminothiazole (tza)] or 2-aminobenzimidazole (abzim)] affords trans-[PdCl2L2] complexes in which the introduced ligands are coordinated to palladium through the endocyclic nitrogen as shown by X-ray crystal structures of trans-[PdCl2(abzt)2]·dmf and trans-[PdCl2(bzta)2]·dmf. Addition of two equivalents of sodium saccharinate (Nasac) yields trans-[Pd(sac)2L2] complexes whereby the saccharinate anions are coordinated through nitrogen as shown by the X-ray crystal structure of trans-[Pd(sac)2(abtz)2]·2dmf. With thiosaccharin (Htsac) trans-[Pd(tsac)2L2] result but now the thiosaccharinate ligands coordinate through the sulfur of the thiolate group as evidenced by spectroscopic studies.

Original language	English
Pages (from-to)	338-343
Number of pages	6
Journal	POLYHEDRON
Volume	67
DOIs	https://doi.org/10.1016/j.poly.2013.09.007
Publication status	Published - 8 Jan 2014

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Al-jibori, S. A., Habeeb, A. T., Al-jibori, G. H. H., Dayaaf, N. A., Merzweiler, K., Wagner, C., Schmidt, H., & Hogarth, G. (2014). Palladium(II) saccharinate (sac) and thiosaccharinate (tsac) complexes with supporting amino- and acetylamino-thiazole ligands: Crystal structures of trans-[PdCl2(abzt)2]·dmf (abzt = 2-aminobenzothiazole), trans-[PdCl2(bzta)2].dmf (bzta = 2-acetylaminobenzothiazole) and trans-[Pd(sac)2(abzt)2]·2dmf. POLYHEDRON, 67, 338-343. https://doi.org/10.1016/j.poly.2013.09.007

Al-jibori, Subhi A. ; Habeeb, Adnan T. ; Al-jibori, Ghassan H.h. et al. / Palladium(II) saccharinate (sac) and thiosaccharinate (tsac) complexes with supporting amino- and acetylamino-thiazole ligands : Crystal structures of trans-[PdCl2(abzt)2]·dmf (abzt = 2-aminobenzothiazole), trans-[PdCl2(bzta)2].dmf (bzta = 2-acetylaminobenzothiazole) and trans-[Pd(sac)2(abzt)2]·2dmf. In: POLYHEDRON. 2014 ; Vol. 67. pp. 338-343.

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title = "Palladium(II) saccharinate (sac) and thiosaccharinate (tsac) complexes with supporting amino- and acetylamino-thiazole ligands: Crystal structures of trans-[PdCl2(abzt)2]·dmf (abzt = 2-aminobenzothiazole), trans-[PdCl2(bzta)2].dmf (bzta = 2-acetylaminobenzothiazole) and trans-[Pd(sac)2(abzt)2]·2dmf",

abstract = "Treatment of Na2PdCl4 with two equivalents of amino- or acetylamino-thiazoles [L = 2-aminobenzothiazole (abzt), 2-aminothiazole (atz), 2-acetylaminobenzothiazole (bzta) and 2-acetylaminothiazole (tza)] or 2-aminobenzimidazole (abzim)] affords trans-[PdCl2L2] complexes in which the introduced ligands are coordinated to palladium through the endocyclic nitrogen as shown by X-ray crystal structures of trans-[PdCl2(abzt)2]·dmf and trans-[PdCl2(bzta)2]·dmf. Addition of two equivalents of sodium saccharinate (Nasac) yields trans-[Pd(sac)2L2] complexes whereby the saccharinate anions are coordinated through nitrogen as shown by the X-ray crystal structure of trans-[Pd(sac)2(abtz)2]·2dmf. With thiosaccharin (Htsac) trans-[Pd(tsac)2L2] result but now the thiosaccharinate ligands coordinate through the sulfur of the thiolate group as evidenced by spectroscopic studies.",

author = "Al-jibori, {Subhi A.} and Habeeb, {Adnan T.} and Al-jibori, {Ghassan H.h.} and Dayaaf, {Noor A.} and Kurt Merzweiler and Christoph Wagner and Harry Schmidt and Graeme Hogarth",

year = "2014",

month = jan,

day = "8",

doi = "10.1016/j.poly.2013.09.007",

language = "English",

volume = "67",

pages = "338--343",

journal = "POLYHEDRON",

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Al-jibori, SA, Habeeb, AT, Al-jibori, GHH, Dayaaf, NA, Merzweiler, K, Wagner, C, Schmidt, H & Hogarth, G 2014, 'Palladium(II) saccharinate (sac) and thiosaccharinate (tsac) complexes with supporting amino- and acetylamino-thiazole ligands: Crystal structures of trans-[PdCl2(abzt)2]·dmf (abzt = 2-aminobenzothiazole), trans-[PdCl2(bzta)2].dmf (bzta = 2-acetylaminobenzothiazole) and trans-[Pd(sac)2(abzt)2]·2dmf', POLYHEDRON, vol. 67, pp. 338-343. https://doi.org/10.1016/j.poly.2013.09.007

Palladium(II) saccharinate (sac) and thiosaccharinate (tsac) complexes with supporting amino- and acetylamino-thiazole ligands: Crystal structures of trans-[PdCl2(abzt)2]·dmf (abzt = 2-aminobenzothiazole), trans-[PdCl2(bzta)2].dmf (bzta = 2-acetylaminobenzothiazole) and trans-[Pd(sac)2(abzt)2]·2dmf. / Al-jibori, Subhi A.; Habeeb, Adnan T.; Al-jibori, Ghassan H.h. et al.
In: POLYHEDRON, Vol. 67, 08.01.2014, p. 338-343.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Palladium(II) saccharinate (sac) and thiosaccharinate (tsac) complexes with supporting amino- and acetylamino-thiazole ligands

T2 - Crystal structures of trans-[PdCl2(abzt)2]·dmf (abzt = 2-aminobenzothiazole), trans-[PdCl2(bzta)2].dmf (bzta = 2-acetylaminobenzothiazole) and trans-[Pd(sac)2(abzt)2]·2dmf

AU - Al-jibori, Subhi A.

AU - Habeeb, Adnan T.

AU - Al-jibori, Ghassan H.h.

AU - Dayaaf, Noor A.

AU - Merzweiler, Kurt

AU - Wagner, Christoph

AU - Schmidt, Harry

AU - Hogarth, Graeme

PY - 2014/1/8

Y1 - 2014/1/8

N2 - Treatment of Na2PdCl4 with two equivalents of amino- or acetylamino-thiazoles [L = 2-aminobenzothiazole (abzt), 2-aminothiazole (atz), 2-acetylaminobenzothiazole (bzta) and 2-acetylaminothiazole (tza)] or 2-aminobenzimidazole (abzim)] affords trans-[PdCl2L2] complexes in which the introduced ligands are coordinated to palladium through the endocyclic nitrogen as shown by X-ray crystal structures of trans-[PdCl2(abzt)2]·dmf and trans-[PdCl2(bzta)2]·dmf. Addition of two equivalents of sodium saccharinate (Nasac) yields trans-[Pd(sac)2L2] complexes whereby the saccharinate anions are coordinated through nitrogen as shown by the X-ray crystal structure of trans-[Pd(sac)2(abtz)2]·2dmf. With thiosaccharin (Htsac) trans-[Pd(tsac)2L2] result but now the thiosaccharinate ligands coordinate through the sulfur of the thiolate group as evidenced by spectroscopic studies.

AB - Treatment of Na2PdCl4 with two equivalents of amino- or acetylamino-thiazoles [L = 2-aminobenzothiazole (abzt), 2-aminothiazole (atz), 2-acetylaminobenzothiazole (bzta) and 2-acetylaminothiazole (tza)] or 2-aminobenzimidazole (abzim)] affords trans-[PdCl2L2] complexes in which the introduced ligands are coordinated to palladium through the endocyclic nitrogen as shown by X-ray crystal structures of trans-[PdCl2(abzt)2]·dmf and trans-[PdCl2(bzta)2]·dmf. Addition of two equivalents of sodium saccharinate (Nasac) yields trans-[Pd(sac)2L2] complexes whereby the saccharinate anions are coordinated through nitrogen as shown by the X-ray crystal structure of trans-[Pd(sac)2(abtz)2]·2dmf. With thiosaccharin (Htsac) trans-[Pd(tsac)2L2] result but now the thiosaccharinate ligands coordinate through the sulfur of the thiolate group as evidenced by spectroscopic studies.

U2 - 10.1016/j.poly.2013.09.007

DO - 10.1016/j.poly.2013.09.007

M3 - Article

SN - 0277-5387

VL - 67

SP - 338

EP - 343

JO - POLYHEDRON

JF - POLYHEDRON

ER -

Al-jibori SA, Habeeb AT, Al-jibori GHH, Dayaaf NA, Merzweiler K, Wagner C et al. Palladium(II) saccharinate (sac) and thiosaccharinate (tsac) complexes with supporting amino- and acetylamino-thiazole ligands: Crystal structures of trans-[PdCl2(abzt)2]·dmf (abzt = 2-aminobenzothiazole), trans-[PdCl2(bzta)2].dmf (bzta = 2-acetylaminobenzothiazole) and trans-[Pd(sac)2(abzt)2]·2dmf. POLYHEDRON. 2014 Jan 8;67:338-343. doi: 10.1016/j.poly.2013.09.007