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Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(ii) centre: A convenient synthesis of Ni(ii)-thiolate complexes

Research output: Contribution to journalArticle

Subhi A. Al-Jibori, Samer Hussein Ali, Ahmed S. Al-Janabi, Christoph Wagner, Graeme Hogarth

Original languageEnglish
Pages (from-to)5520-5522
Number of pages3
JournalDalton Transactions
Volume48
Issue number17
DOIs
Publication statusPublished - 23 Apr 2019

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Abstract

Phosphines react with the benzisothiazolinate (bit) paddlewheel dimer, [Ni 2 (μ-bit) 4 ·2H 2 O], resulting in sulfur-nitrogen bond scission and a series of unexpected transformations leading to novel Ni(ii) complexes containing 2-cyanophenylthiolate and related thiolate ligands.

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