Rigidity extremes in coordination chemistry: A fine energetic balance in the isolation of a trapped ligand inversion intermediate

Caleb M. May; Stephen J. Archibald; Adam J. Bridgeman; Christopher J. Empson; Timothy J. Hubin

doi:10.1039/b405358c

Rigidity extremes in coordination chemistry: A fine energetic balance in the isolation of a trapped ligand inversion intermediate

Caleb M. May
, Stephen J. Archibald
, Adam J. Bridgeman
, Christopher J. Empson
, Timothy J. Hubin^*

^*Corresponding author for this work

Imaging Chemistry & Biology

McPherson College
Department of Chemistry
University of Hull

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

An unusual copper(II) complex of a highly rigid and bulky ligand (a macrocycle-glyoxal condensate) has been synthesized and investigated via DFT calculations and structural characterisation.

Original language	English
Pages (from-to)	1880-1881
Number of pages	2
Journal	Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/b405358c
Publication status	Published - 21 Aug 2004

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10.1039/b405358c

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title = "Rigidity extremes in coordination chemistry: A fine energetic balance in the isolation of a trapped ligand inversion intermediate",

abstract = "An unusual copper(II) complex of a highly rigid and bulky ligand (a macrocycle-glyoxal condensate) has been synthesized and investigated via DFT calculations and structural characterisation.",

author = "May, \{Caleb M.\} and Archibald, \{Stephen J.\} and Bridgeman, \{Adam J.\} and Empson, \{Christopher J.\} and Hubin, \{Timothy J.\}",

year = "2004",

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doi = "10.1039/b405358c",

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T1 - Rigidity extremes in coordination chemistry

T2 - A fine energetic balance in the isolation of a trapped ligand inversion intermediate

AU - May, Caleb M.

AU - Archibald, Stephen J.

AU - Bridgeman, Adam J.

AU - Empson, Christopher J.

AU - Hubin, Timothy J.

PY - 2004/8/21

Y1 - 2004/8/21

N2 - An unusual copper(II) complex of a highly rigid and bulky ligand (a macrocycle-glyoxal condensate) has been synthesized and investigated via DFT calculations and structural characterisation.

AB - An unusual copper(II) complex of a highly rigid and bulky ligand (a macrocycle-glyoxal condensate) has been synthesized and investigated via DFT calculations and structural characterisation.

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U2 - 10.1039/b405358c

DO - 10.1039/b405358c

M3 - Article

AN - SCOPUS:4644296352

SN - 1359-7345

SP - 1880

EP - 1881

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

Rigidity extremes in coordination chemistry: A fine energetic balance in the isolation of a trapped ligand inversion intermediate

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