Stable metal-organic frameworks with low water affinity built from methyl-siloxane linkers

Luke C. Delmas, Andrew J.P. White, David Pugh, Arwyn Evans, Mark Antonin Isbell, Jerry Y.Y. Heng, Paul D. Lickiss, Robert P. Davies

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

A tetracarboxylic acid with a methyl-substituted siloxane core (L-H4) has been prepared and applied in the construction of water stable MOFs with low water affinity. L-H4 itself crystallizes as an interpenetrated 3D hydrogen-bonded network. Reaction of L-H4 with ZrIV/HfIV gave IMP-32-Zr/Hf-both 3D MOFs of scu topology.

Original languageEnglish
Pages (from-to)7905-7908
Number of pages4
JournalChemical Communications
Volume56
Issue number57
DOIs
Publication statusPublished - 21 Jul 2020

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