STRUCTURE AND ABSOLUTE STEREOCHEMISTRY OF CYCLOLINTEINONE, A NOVEL MONOCARBOCYCLIC SESTERTERPENE FROM CACOSPONGIA CF LINTEIFORMIS

M R  CONTE; E  FATTORUSSO; V  LANZOTTI; S  MAGNO; L  MAYOL

STRUCTURE AND ABSOLUTE STEREOCHEMISTRY OF CYCLOLINTEINONE, A NOVEL MONOCARBOCYCLIC SESTERTERPENE FROM CACOSPONGIA CF LINTEIFORMIS

M R CONTE, E FATTORUSSO, V LANZOTTI, S MAGNO, L MAYOL

University of Naples Federico II

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

A novel sesterterpene, cyclolinteinone (4), based on an unprecedented rearranged monocarbocyclic skeleton, has been isolated from Cacospongia cf. linteiformis, and its structure, complete with absolute stereochemistry, determined by spectral studies and chemical correlations. A plausible pathway for the biogenesis of this compound starting from geranylfarnesol is proposed. Cyclolinteinone has been shown to possess high ichthyotoxicity and antifeedant properties.

Original language	English
Pages (from-to)	13469-13476
Number of pages	8
Journal	TETRAHEDRON
Volume	50
Issue number	47
Publication status	Published - 21 Nov 1994

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title = "STRUCTURE AND ABSOLUTE STEREOCHEMISTRY OF CYCLOLINTEINONE, A NOVEL MONOCARBOCYCLIC SESTERTERPENE FROM CACOSPONGIA CF LINTEIFORMIS",

abstract = "A novel sesterterpene, cyclolinteinone (4), based on an unprecedented rearranged monocarbocyclic skeleton, has been isolated from Cacospongia cf. linteiformis, and its structure, complete with absolute stereochemistry, determined by spectral studies and chemical correlations. A plausible pathway for the biogenesis of this compound starting from geranylfarnesol is proposed. Cyclolinteinone has been shown to possess high ichthyotoxicity and antifeedant properties.",

author = "CONTE, {M R} and E FATTORUSSO and V LANZOTTI and S MAGNO and L MAYOL",

year = "1994",

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T1 - STRUCTURE AND ABSOLUTE STEREOCHEMISTRY OF CYCLOLINTEINONE, A NOVEL MONOCARBOCYCLIC SESTERTERPENE FROM CACOSPONGIA CF LINTEIFORMIS

AU - CONTE, M R

AU - FATTORUSSO, E

AU - LANZOTTI, V

AU - MAGNO, S

AU - MAYOL, L

PY - 1994/11/21

Y1 - 1994/11/21

N2 - A novel sesterterpene, cyclolinteinone (4), based on an unprecedented rearranged monocarbocyclic skeleton, has been isolated from Cacospongia cf. linteiformis, and its structure, complete with absolute stereochemistry, determined by spectral studies and chemical correlations. A plausible pathway for the biogenesis of this compound starting from geranylfarnesol is proposed. Cyclolinteinone has been shown to possess high ichthyotoxicity and antifeedant properties.

AB - A novel sesterterpene, cyclolinteinone (4), based on an unprecedented rearranged monocarbocyclic skeleton, has been isolated from Cacospongia cf. linteiformis, and its structure, complete with absolute stereochemistry, determined by spectral studies and chemical correlations. A plausible pathway for the biogenesis of this compound starting from geranylfarnesol is proposed. Cyclolinteinone has been shown to possess high ichthyotoxicity and antifeedant properties.

M3 - Article

SN - 0040-4020

VL - 50

SP - 13469

EP - 13476

JO - TETRAHEDRON

JF - TETRAHEDRON

IS - 47

ER -

STRUCTURE AND ABSOLUTE STEREOCHEMISTRY OF CYCLOLINTEINONE, A NOVEL MONOCARBOCYCLIC SESTERTERPENE FROM CACOSPONGIA CF LINTEIFORMIS

Abstract

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