Substituted ferrocenes and iodine as synergistic thermoelectrochemical heat harvesting redox couples in ionic liquids

E. H. B. Anari; M. Romano; W. X. Teh; J. J. Black; E. Jiang; J. Chen; T. Q. To; J. Panchompoo; L. Aldous

doi:10.1039/c5cc05889a

Substituted ferrocenes and iodine as synergistic thermoelectrochemical heat harvesting redox couples in ionic liquids

E. H. B. Anari, M. Romano, W. X. Teh, J. J. Black, E. Jiang, J. Chen, T. Q. To, J. Panchompoo, L. Aldous

Chemistry

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Abstract

Combining ferrocene and iodine results in enhanced
thermoelectrochemical (or thermogalvanic) waste heat harvesting
abilities, for both the Seebeck coefficient and the overall power
output. All systems displayed a mixture of ferrocene, ferrocenium,
iodine and triiodide. The observed enhancement correlates with
lower electron-density on the ferrocene; the synergistic
improvement observed for mixtures of substituted ferrocenes and
iodine is attributed to the formation of charge-transfer complexes.
Combining dibutanoylferrocene and iodine resulted in the highest
Seebeck coefficient of 1.67 mV K-1

Original language	English
Pages (from-to)	745-748
Journal	CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRY
Volume	52
Issue number	4
Early online date	4 Nov 2015
DOIs	https://doi.org/10.1039/c5cc05889a
Publication status	Published - 2016

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10.1039/c5cc05889a

0080 - Anari - FcI3 - Chem. Commun. - 2016
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Cite this

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title = "Substituted ferrocenes and iodine as synergistic thermoelectrochemical heat harvesting redox couples in ionic liquids",

abstract = "Combining ferrocene and iodine results in enhanced thermoelectrochemical (or thermogalvanic) waste heat harvesting abilities, for both the Seebeck coefficient and the overall power output. All systems displayed a mixture of ferrocene, ferrocenium, iodine and triiodide. The observed enhancement correlates with lower electron-density on the ferrocene; the synergistic improvement observed for mixtures of substituted ferrocenes and iodine is attributed to the formation of charge-transfer complexes. Combining dibutanoylferrocene and iodine resulted in the highest Seebeck coefficient of 1.67 mV K-1",

author = "Anari, {E. H. B.} and M. Romano and Teh, {W. X.} and Black, {J. J.} and E. Jiang and J. Chen and To, {T. Q.} and J. Panchompoo and L. Aldous",

year = "2016",

doi = "10.1039/c5cc05889a",

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TY - JOUR

T1 - Substituted ferrocenes and iodine as synergistic thermoelectrochemical heat harvesting redox couples in ionic liquids

AU - Anari, E. H. B.

AU - Romano, M.

AU - Teh, W. X.

AU - Black, J. J.

AU - Jiang, E.

AU - Chen, J.

AU - To, T. Q.

AU - Panchompoo, J.

AU - Aldous, L.

PY - 2016

Y1 - 2016

N2 - Combining ferrocene and iodine results in enhanced thermoelectrochemical (or thermogalvanic) waste heat harvesting abilities, for both the Seebeck coefficient and the overall power output. All systems displayed a mixture of ferrocene, ferrocenium, iodine and triiodide. The observed enhancement correlates with lower electron-density on the ferrocene; the synergistic improvement observed for mixtures of substituted ferrocenes and iodine is attributed to the formation of charge-transfer complexes. Combining dibutanoylferrocene and iodine resulted in the highest Seebeck coefficient of 1.67 mV K-1

AB - Combining ferrocene and iodine results in enhanced thermoelectrochemical (or thermogalvanic) waste heat harvesting abilities, for both the Seebeck coefficient and the overall power output. All systems displayed a mixture of ferrocene, ferrocenium, iodine and triiodide. The observed enhancement correlates with lower electron-density on the ferrocene; the synergistic improvement observed for mixtures of substituted ferrocenes and iodine is attributed to the formation of charge-transfer complexes. Combining dibutanoylferrocene and iodine resulted in the highest Seebeck coefficient of 1.67 mV K-1

U2 - 10.1039/c5cc05889a

DO - 10.1039/c5cc05889a

M3 - Article

SN - 1359-7345

VL - 52

SP - 745

EP - 748

JO - CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRY

JF - CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRY

IS - 4

ER -

Substituted ferrocenes and iodine as synergistic thermoelectrochemical heat harvesting redox couples in ionic liquids

Abstract

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