Synthesis of functionalised (triorganostannyl)tetrazoles: Supramolecular structures of w-[2-(triorganostannyl)tetrazol-5-yl]-pyridine (n -2, 3 or 4)1

Sonali Bhandari; Christopher G. Frost; Catherine E. Hague; Mary F. Mahon; Kieranc Molloy

doi:10.1039/a908380d

Synthesis of functionalised (triorganostannyl)tetrazoles: Supramolecular structures of w-[2-(triorganostannyl)tetrazol-5-yl]-pyridine (n -2, 3 or 4)1

Sonali Bhandari^*, Christopher G. Frost, Catherine E. Hague, Mary F. Mahon, Kieranc Molloy

^*Corresponding author for this work

Chemistry

University of Bath

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

Six pyridine-substituted triorganostannyltetrazoles, /i-[2-(triorganostannyl)tetrazol-5-yl]pyridine (n = 2, 3 or 4; R = Et or Bu), have been synthesized by a cycloaddition method involving R3SnN3 and w-cyanopyridine. 1,7-Bis[2-{(triorganostannyl)tetrazol-5-yl}phenyl]-l,4,7-trioxaheptane has been synthesized by the cycloaddition of tributyltin azide and 1,7-di(2-cyanophenyl)-1,4,7-trioxaheptane. The crystal structures of 3-(EtjSnN₄C)C₅H₄N-H₂O, 4-(Et₃SnN₄C)C₅H₄N and 4-(Bu₃SnN₄C)C₅H₄N-₂H ₂O, have been determined. While the first and third are three-dimensional arrays held together by hydrogen bonds, the supramolecular structure of the anhydrous second consists of one-dimensional helical polymers.

Original language	English
Pages (from-to)	663-669
Number of pages	7
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	5
DOIs	https://doi.org/10.1039/a908380d
Publication status	Published - 2000

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@article{75871104c6844734b5c5a3573f1a4501,

title = "Synthesis of functionalised (triorganostannyl)tetrazoles: Supramolecular structures of w-[2-(triorganostannyl)tetrazol-5-yl]-pyridine (n -2, 3 or 4)1",

abstract = "Six pyridine-substituted triorganostannyltetrazoles, /i-[2-(triorganostannyl)tetrazol-5-yl]pyridine (n = 2, 3 or 4; R = Et or Bu), have been synthesized by a cycloaddition method involving R3SnN3 and w-cyanopyridine. 1,7-Bis[2-{(triorganostannyl)tetrazol-5-yl}phenyl]-l,4,7-trioxaheptane has been synthesized by the cycloaddition of tributyltin azide and 1,7-di(2-cyanophenyl)-1,4,7-trioxaheptane. The crystal structures of 3-(EtjSnN4C)C5H4N-H2O, 4-(Et3SnN4C)C5H4N and 4-(Bu3SnN4C)C5H4N-2H 2O, have been determined. While the first and third are three-dimensional arrays held together by hydrogen bonds, the supramolecular structure of the anhydrous second consists of one-dimensional helical polymers.",

author = "Sonali Bhandari and Frost, {Christopher G.} and Hague, {Catherine E.} and Mahon, {Mary F.} and Kieranc Molloy",

year = "2000",

doi = "10.1039/a908380d",

language = "English",

pages = "663--669",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "5",

}

Synthesis of functionalised (triorganostannyl)tetrazoles: Supramolecular structures of w-[2-(triorganostannyl)tetrazol-5-yl]-pyridine (n -2, 3 or 4)1. / Bhandari, Sonali; Frost, Christopher G.; Hague, Catherine E. et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 5, 2000, p. 663-669.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis of functionalised (triorganostannyl)tetrazoles

T2 - Supramolecular structures of w-[2-(triorganostannyl)tetrazol-5-yl]-pyridine (n -2, 3 or 4)1

AU - Bhandari, Sonali

AU - Frost, Christopher G.

AU - Hague, Catherine E.

AU - Mahon, Mary F.

AU - Molloy, Kieranc

PY - 2000

Y1 - 2000

N2 - Six pyridine-substituted triorganostannyltetrazoles, /i-[2-(triorganostannyl)tetrazol-5-yl]pyridine (n = 2, 3 or 4; R = Et or Bu), have been synthesized by a cycloaddition method involving R3SnN3 and w-cyanopyridine. 1,7-Bis[2-{(triorganostannyl)tetrazol-5-yl}phenyl]-l,4,7-trioxaheptane has been synthesized by the cycloaddition of tributyltin azide and 1,7-di(2-cyanophenyl)-1,4,7-trioxaheptane. The crystal structures of 3-(EtjSnN4C)C5H4N-H2O, 4-(Et3SnN4C)C5H4N and 4-(Bu3SnN4C)C5H4N-2H 2O, have been determined. While the first and third are three-dimensional arrays held together by hydrogen bonds, the supramolecular structure of the anhydrous second consists of one-dimensional helical polymers.

AB - Six pyridine-substituted triorganostannyltetrazoles, /i-[2-(triorganostannyl)tetrazol-5-yl]pyridine (n = 2, 3 or 4; R = Et or Bu), have been synthesized by a cycloaddition method involving R3SnN3 and w-cyanopyridine. 1,7-Bis[2-{(triorganostannyl)tetrazol-5-yl}phenyl]-l,4,7-trioxaheptane has been synthesized by the cycloaddition of tributyltin azide and 1,7-di(2-cyanophenyl)-1,4,7-trioxaheptane. The crystal structures of 3-(EtjSnN4C)C5H4N-H2O, 4-(Et3SnN4C)C5H4N and 4-(Bu3SnN4C)C5H4N-2H 2O, have been determined. While the first and third are three-dimensional arrays held together by hydrogen bonds, the supramolecular structure of the anhydrous second consists of one-dimensional helical polymers.

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DO - 10.1039/a908380d

M3 - Article

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SN - 1470-479X

SP - 663

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JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

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ER -

Synthesis of functionalised (triorganostannyl)tetrazoles: Supramolecular structures of w-[2-(triorganostannyl)tetrazol-5-yl]-pyridine (n -2, 3 or 4)1

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