King's College London

Research portal

Voltage and Redox State Triggered Oxygen Adatom Conductance Switch

Research output: Contribution to journalArticlepeer-review

Quanzhen Zhang, J. Brndiar, Yuuki Adachi, Martin Konopka, Huan Fei Wen, Masato Miyazaki, Yasuhiro Sugawara, Rui Xu, Zhi Hai Cheng, Hongqian Sang, Yan Jun Li, Lev Kantorovich, Ivan Stich

Original languageEnglish
JournalJournal Of Physical Chemistry C
Accepted/In press2 Nov 2021

King's Authors


Switches are omnipresent in all electronic de- vices. Miniaturization reduced the size of switches down to atomic dimensions. While on-surface tip-tuned molecular switches have recently been widely studied, atomic switches have received much less attention despite the fact that they could, in addition to the size, reduce also the switching times by orders of magnitude by tuning directly their electronic, rather than atomic states. We have studied an ultra-fast tip-tuned conductance switch which can switch reversibly and repeatably by ap- plied bias. The switch is realized by an oxygen adatom supported on rutile TiO2 surface whose redox state can be switched between -1, -2, or 0, the former being conducting, the latter two nonconducting. Advanced simulations suggest that for virtually identical current-bias traces several mechanisms, such as discharge/recharge via a state of a nearby polaron or via a highly energetically unfavorable neutral redox state are involved.

View graph of relations

© 2020 King's College London | Strand | London WC2R 2LS | England | United Kingdom | Tel +44 (0)20 7836 5454